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Assertion : Aromatic aldehydes and forma...

Assertion : Aromatic aldehydes and formaldehyde undergo Cannizzaro reaction
Reason : Aromatic aldehydes are almost as reactive as formaldehyde.

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To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that "Aromatic aldehydes and formaldehyde undergo Cannizzaro reaction." The Cannizzaro reaction is a redox reaction that occurs in aldehydes that do not have alpha-hydrogens. **Hint:** Recall that the Cannizzaro reaction is favored by aldehydes without alpha-hydrogens. ### Step 2: Identify Aldehydes Formaldehyde (HCHO) does not have any alpha-hydrogens. Aromatic aldehydes, such as benzaldehyde (C6H5CHO), also lack alpha-hydrogens. Therefore, both formaldehyde and aromatic aldehydes can undergo the Cannizzaro reaction. **Hint:** Check the structure of the aldehydes to confirm the absence of alpha-hydrogens. ### Step 3: Analyze the Reason The reason states that "Aromatic aldehydes are almost as reactive as formaldehyde." To evaluate this, we need to consider the reactivity of formaldehyde compared to aromatic aldehydes. **Hint:** Consider the electrophilicity of the carbonyl carbon in formaldehyde versus aromatic aldehydes. ### Step 4: Compare Reactivity Formaldehyde is more reactive than aromatic aldehydes because it has no alkyl groups attached to the carbonyl carbon, making it more electrophilic. In contrast, aromatic aldehydes have an aromatic ring, which can donate electron density to the carbonyl carbon, reducing its electrophilicity and, therefore, its reactivity. **Hint:** Remember that electron-donating groups decrease the electrophilicity of the carbonyl carbon. ### Step 5: Conclusion Since the assertion is true (both types of aldehydes can undergo the Cannizzaro reaction) and the reason is false (aromatic aldehydes are not as reactive as formaldehyde), we conclude that: - **Assertion:** True - **Reason:** False **Final Answer:** The assertion is correct, but the reason is incorrect.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that "Aromatic aldehydes and formaldehyde undergo Cannizzaro reaction." The Cannizzaro reaction is a redox reaction that occurs in aldehydes that do not have alpha-hydrogens. **Hint:** Recall that the Cannizzaro reaction is favored by aldehydes without alpha-hydrogens. ### Step 2: Identify Aldehydes ...
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What type of aldehydes undergo Cannizzaro's reaction?

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Knowledge Check

  • Assertion : Aromatic aldehydes and formaldehyde undergo Cannizzaro reaction. Reason : Those aldehydes which have alpha -H atom undergo Cannizzaro reaction.

    A
    If both assertion and reason are true and reason is the correct explanation of assertion.
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion.
    C
    If assertion is true but reason is false.
    D
    If both assertion and reason are false.
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    What type of aldehydes undergo Cannizzaro's reaction?

    Why does formaldehyde undergo Cannizzaro's reaction while acetaldehyde gives aldol condensation?

    Formaldehyde undergoes Cannizzaro's reaction since it has one alpha hydrogen atom.

    Formaldehyde undergoes Cannizzaro's reaction since it has one alpha hydrogen atom.

    Formaldehyde undergoes Cannizzaro's reaction since it has one alpha hydrogen atom.

    Formaldehyde gives Cannizzaro's reaction while acetaldehyde does not. Why ?

    p-Hydroxybenzaldehyde does not undergo Cannizzaro reaction. Explain.