Home
Class 12
CHEMISTRY
Assertion : Aromatic aldehydes and forma...

Assertion : Aromatic aldehydes and formaldehyde undergo Cannizzaro reaction
Reason : Aromatic aldehydes are almost as reactive as formaldehyde.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that "Aromatic aldehydes and formaldehyde undergo Cannizzaro reaction." The Cannizzaro reaction is a redox reaction that occurs in aldehydes that do not have alpha-hydrogens. **Hint:** Recall that the Cannizzaro reaction is favored by aldehydes without alpha-hydrogens. ### Step 2: Identify Aldehydes Formaldehyde (HCHO) does not have any alpha-hydrogens. Aromatic aldehydes, such as benzaldehyde (C6H5CHO), also lack alpha-hydrogens. Therefore, both formaldehyde and aromatic aldehydes can undergo the Cannizzaro reaction. **Hint:** Check the structure of the aldehydes to confirm the absence of alpha-hydrogens. ### Step 3: Analyze the Reason The reason states that "Aromatic aldehydes are almost as reactive as formaldehyde." To evaluate this, we need to consider the reactivity of formaldehyde compared to aromatic aldehydes. **Hint:** Consider the electrophilicity of the carbonyl carbon in formaldehyde versus aromatic aldehydes. ### Step 4: Compare Reactivity Formaldehyde is more reactive than aromatic aldehydes because it has no alkyl groups attached to the carbonyl carbon, making it more electrophilic. In contrast, aromatic aldehydes have an aromatic ring, which can donate electron density to the carbonyl carbon, reducing its electrophilicity and, therefore, its reactivity. **Hint:** Remember that electron-donating groups decrease the electrophilicity of the carbonyl carbon. ### Step 5: Conclusion Since the assertion is true (both types of aldehydes can undergo the Cannizzaro reaction) and the reason is false (aromatic aldehydes are not as reactive as formaldehyde), we conclude that: - **Assertion:** True - **Reason:** False **Final Answer:** The assertion is correct, but the reason is incorrect.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understand the Assertion The assertion states that "Aromatic aldehydes and formaldehyde undergo Cannizzaro reaction." The Cannizzaro reaction is a redox reaction that occurs in aldehydes that do not have alpha-hydrogens. **Hint:** Recall that the Cannizzaro reaction is favored by aldehydes without alpha-hydrogens. ### Step 2: Identify Aldehydes ...
Promotional Banner

Topper's Solved these Questions

  • ALDEHYDE, KETONES AND CARBOXYLIC ACIDS

    NCERT EXEMPLAR ENGLISH|Exercise Long Answer Type Questions|4 Videos
  • ALDEHYDE, KETONES AND CARBOXYLIC ACIDS

    NCERT EXEMPLAR ENGLISH|Exercise Long Answer Type Questions|4 Videos
  • ALCOHOLS, PHENOLS AND ETHERS

    NCERT EXEMPLAR ENGLISH|Exercise All Questions|74 Videos
  • AMINES

    NCERT EXEMPLAR ENGLISH|Exercise LONG ANSWER|3 Videos

Similar Questions

Explore conceptually related problems

What type of aldehydes undergo Cannizzaro's reaction?

Assertion : Aromatic aldehydes and formaldehyde undergo Cannizzaro reaction. Reason : Those aldehydes which have alpha -H atom undergo Cannizzaro reaction.

Why does formaldehyde undergo Cannizzaro's reaction while acetaldehyde gives aldol condensation?

Formaldehyde gives Cannizzaro's reaction while acetaldehyde does not. Why ?

p-Hydroxybenzaldehyde does not undergo Cannizzaro reaction. Explain.

NCERT EXEMPLAR ENGLISH-ALDEHYDE, KETONES AND CARBOXYLIC ACIDS-Short Answer Type Questions
  1. Arrange the following in decreasing order of their acidic strength and...

    Text Solution

    |

  2. What product will be formed on reaction of propanal with 2-methylpropa...

    Text Solution

    |

  3. Compound 'A' is prepared by oxidation of compound 'B' with alkaline KM...

    Text Solution

    |

  4. Arrange the following in decreasing order of their acidic strength. Gi...

    Text Solution

    |

  5. Alkenes and carbonyl compounds both contain a pi bond but alkenes sh...

    Text Solution

    |

  6. Carboxylic acids contain carbonyl group but do not show the nucleophil...

    Text Solution

    |

  7. Identify the compounds A, B and C in the following reaction : CH(3)-...

    Text Solution

    |

  8. Why are carboxylic acids more acidic than alcohols or phenols although...

    Text Solution

    |

  9. Complete the following reaction sequence : CH(3)-overset(O)overset(|...

    Text Solution

    |

  10. Ethylbenzene is generally prepared by acetylation of benzene followed ...

    Text Solution

    |

  11. Can Gattermann-Koch reaction be considered similar to Friedel Craft's ...

    Text Solution

    |

  12. Match the common names given in Column I with the IUPAC names given in...

    Text Solution

    |

  13. Match the acids given in Column I with their correct IUPAC names given...

    Text Solution

    |

  14. Match the reactions given in Column I with the suitable reagents given...

    Text Solution

    |

  15. Match the example given in Column I with the name of the reaction in C...

    Text Solution

    |

  16. Assertion (A) Formaldehyde is a planar molecule. Reason (R) It conta...

    Text Solution

    |

  17. Assertion (A) compound containing -CHO group are easily oxidised to co...

    Text Solution

    |

  18. Assertion (A) The alpha-hydrogen atom in carbonyl compounds is less ac...

    Text Solution

    |

  19. Assertion : Aromatic aldehydes and formaldehyde undergo Cannizzaro rea...

    Text Solution

    |

  20. Assertion (A) Aldehydes and ketones, both react with Tollen's reagent ...

    Text Solution

    |