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Some alkyl halides undergo substitution ...

Some alkyl halides undergo substitution whereas some undergo elimination reaction on treatment with bases. Discuss the structural features of alkyl halides with the help of examples which are responsible for this difference.

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To understand why some alkyl halides undergo substitution reactions while others undergo elimination reactions when treated with bases, we need to consider the structural features of the alkyl halides and the nature of the bases used. Here’s a step-by-step explanation: ### Step 1: Understand the Types of Reactions Alkyl halides can undergo two main types of reactions when treated with bases: - **Substitution Reactions (SN1/SN2)**: In these reactions, a nucleophile replaces the halogen atom in the alkyl halide. - **Elimination Reactions (E1/E2)**: In these reactions, the alkyl halide loses a halogen and a hydrogen atom, resulting in the formation of a double bond. ### Step 2: Identify the Role of the Base ...
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Assertion: Aryl halides undergo nucleophilic substitution reactions with ease. Reason:The carbon halogen bond in aryl halides has partial double bonds character.

A primary alkyl halide would prefer to undergo :-

Knowledge Check

  • The compound shown in the below undergoes racemization on reaction with aqueous acid. Which of the following structures best represents the intermediate responsible for this process ?

    A
    B
    C
    D
  • Which of the following alkyl halide undergo rearrangement in S_(N^1) reaction ?

    A
    `CH_(3)-overset(CH_3)overset(|)underset(CH_3)underset(|)C-underset(I)underset(|)CH-CH_(3)`
    B
    C
    D
    All of these
  • Which of the following statement is not correct about S_(N^2) reactions of alkyl halides?

    A
    Nucleophile attacks the carbon from the side opposite to where the leaving group is attached.
    B
    The bond formation and bond breaking take place in one step.
    C
    The rate of reaction depends upon the concentration of nucleophile.
    D
    `S_(N^2)` mechanism is predominant in tertiary alkyl halides.
  • Similar Questions

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    1^(@) alkyl halides preferably undergo which of the following mechanism ?

    Which of the following is an example of aryl alkyl halide ?

    A primary alkyl halide would prefer to undergo :-

    Which of the following halides undergo E_(2) elimination?

    Aryl halides are less reactive towards nucleophilic substitution reaction as compared to alkyl halides due to