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Which of the following is correct for P(...

Which of the following is correct for `P_(4)` molecule of white phosphorus ?

A

It has 6 lone pairs of electrons

B

lt has six P___P single bonds

C

It has three P____P single bonds

D

It has lone pair of electron

Text Solution

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The correct Answer is:
To determine the correct statements about the `P₄` molecule of white phosphorus, we can analyze its structure and bonding characteristics step by step. ### Step 1: Understanding the Structure of P₄ The `P₄` molecule consists of four phosphorus atoms arranged in a tetrahedral shape. Each phosphorus atom is bonded to three other phosphorus atoms. ### Step 2: Counting the Bonds In the `P₄` molecule, each phosphorus atom forms three single bonds with the other phosphorus atoms. Therefore, we can count the total number of P-P bonds: - Each P atom forms 3 bonds. - Since there are 4 P atoms, the total number of P-P bonds is 4 (as each bond is counted twice). ### Step 3: Determining Lone Pairs Each phosphorus atom has 5 valence electrons. In the `P₄` structure: - Each phosphorus atom uses 3 of its valence electrons to form bonds with other phosphorus atoms. - This leaves each phosphorus atom with 2 unshared electrons, which are considered lone pairs. Since there are 4 phosphorus atoms, the total number of lone pairs in the `P₄` molecule is: - 4 phosphorus atoms × 1 lone pair per atom = 4 lone pairs. ### Step 4: Summary of Findings Based on the analysis: - The `P₄` molecule has a total of 4 lone pairs of electrons. - It has a total of 6 P-P single bonds. ### Conclusion The correct statements regarding the `P₄` molecule of white phosphorus are: 1. It has 4 lone pairs of electrons. 2. It has 6 P-P single bonds.

To determine the correct statements about the `P₄` molecule of white phosphorus, we can analyze its structure and bonding characteristics step by step. ### Step 1: Understanding the Structure of P₄ The `P₄` molecule consists of four phosphorus atoms arranged in a tetrahedral shape. Each phosphorus atom is bonded to three other phosphorus atoms. ### Step 2: Counting the Bonds In the `P₄` molecule, each phosphorus atom forms three single bonds with the other phosphorus atoms. Therefore, we can count the total number of P-P bonds: - Each P atom forms 3 bonds. ...
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Knowledge Check

  • Which of the following are correct regarding these molecule.

    A
    Both compounds contain plane of symmetry
    B
    Both are enantiomers
    C
    Both are diastereomers of each other
    D
    None of these
  • Which of the following is not the characteristic of a white phosphorus ( P_4 ) molecule?

    A
    Presence of six P-P single bonds
    B
    Presence of four P-P single bonds
    C
    Presence of four lone pairs of electrons
    D
    Presence of PPP angle of `60^@`
  • The structure of white phosphorus is

    A
    square planar
    B
    pyramidal
    C
    tetrahedral
    D
    trigonal planar
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