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Fe show on oxidation state of +1 in:...

Fe show on oxidation state of +1 in:

A

`Fe(CO)_(5)`

B

`[Fe(H_(2)O)_(5)NO]SO_(4)`

C

`Fe_(4)[Fe(CN)_(6)]_(3)`

D

`Fe_(4)Cl_(4)^(-)`

Text Solution

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The correct Answer is:
To determine in which compound iron (Fe) shows an oxidation state of +1, we can analyze various compounds of iron and calculate the oxidation state in each case. ### Step-by-Step Solution: **Step 1: Analyze the compound FeCO5** - In FeCO5, the oxidation state of the carbonyl group (CO) is 0. - Let the oxidation state of iron be \( x \). - The total oxidation state for the compound is \( x + 5(0) = x \). - Since CO is neutral, the oxidation state of Fe in FeCO5 is 0. - Therefore, Fe does not show +1 oxidation state in this compound. **Step 2: Analyze the compound FeH2O5** - In FeH2O5, we need to consider the oxidation states of water (H2O) and other components. - The oxidation state of water is 0. - Let the oxidation state of iron be \( x \). - The total oxidation state for the compound is \( x + 5(0) = x \). - Therefore, we cannot conclude the oxidation state of Fe in this compound directly. **Step 3: Analyze the compound NO+** - In NO+, the oxidation state of nitrogen (N) is +2. - Let the oxidation state of iron be \( x \). - The total oxidation state for the compound is \( x + 2 = +1 \). - Rearranging gives \( x = +1 - 2 = -1 \). - This indicates that Fe does not show +1 oxidation state in this compound. **Step 4: Analyze the compound FeSO4** - In FeSO4, the oxidation state of sulfate (SO4) is -2. - Let the oxidation state of iron be \( x \). - The total oxidation state for the compound is \( x + (-2) = 0 \). - Rearranging gives \( x = +2 \). - Therefore, Fe does not show +1 oxidation state in this compound either. **Step 5: Conclusion** - After analyzing the compounds FeCO5, FeH2O5, NO+, and FeSO4, we find that iron shows an oxidation state of +1 in the compound **FeH2O5**. ### Final Answer: Iron (Fe) shows an oxidation state of +1 in the compound **FeH2O5**.
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