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When an electron withdrawing or electron releasing group is attached to carbon chain, polarity is induced on the carbon atom and on the substituent attach to it. This permanent polarity is due electron displacement due to difference in electronegativities this is called inductive effect or I effect. The inducitve effect depends in the electronegativity of the substituent. The inductive effect is broadly classified as (i) negative inductive effect or -I effect. (ii) positive inductive effect or +I effect.
Stability of given anions in the decreasing order is
(i) `bar(C)H_(3) " (ii) "bar(C)H_(2)-NO_(2)" (iii) "bar(C)H_(2)Cl" (iv) "CH_(3)-bar(C)H_(2)`

A

`i gt ii gt iii gt iv`

B

`ii gt iii gt igt iv`

C

`ii gt igt iii gt iv`

D

`iv gt igt iii gt ii`

Text Solution

Verified by Experts

The correct Answer is:
D
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Knowledge Check

  • When an electron withdrawing or electron releasing group is attached to carbon chain, polarity is induced on the carbon atom and on the substituent attach to it. This permanent polarity is due electron displacement due to difference in electronegativities this is called inductive effect or I effect. The inducitve effect depends in the electronegativity of the substituent. The inductive effect is broadly classified as (i) negative inductive effect or -I effect. (ii) positive inductive effect or +I effect. The group which exhibits the maximum -I effect

    A
    `-NO_(2)`
    B
    `-CN`
    C
    `-Cl`
    D
    `-OH`

  • When an electron withdrawing or electron releasing group is attached to carbon chain, polarity is induced on the carbon atom and on the substituent attach to it. This permanent polarity is due electron displacement due to difference in electronegativities this is called inductive effect or I effect. The inducitve effect depends in the electronegativity of the substituent. The inductive effect is broadly classified as (i) negative inductive effect or -I effect. (ii) positive inductive effect or +I effect. The group which exhibits the maximum -I effect

    A
    `-NO_(2)`
    B
    `-CN`
    C
    `-Cl`
    D
    `-OH`

  • When an electron withdrawing or electron releasing group is attached to carbon chain, polarity is induced on the carbon atom and on the substituent attach to it. This permanent polarity is due electron displacement due to difference in electronegativities this is called inductive effect or I effect. The inducitve effect depends in the electronegativity of the substituent. The inductive effect is broadly classified as (i) negative inductive effect or -I effect. (ii) positive inductive effect or +I effect. Which of the following statements is correct about inductive effect ?

    A
    Polarization of a `sigma-` bond is called inductive effect.
    B
    Inductive effect is transmitted through `sigma-` bonds
    C
    Inductive effective is transmitted through `pi-` bond
    D
    Both a and b.

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    Write examples for electron releasing and electron withdrawing groups.

    When an electron withdrawing or electron releasing group is attached to carbon chain, polarity is induced on the carbon atom and on the substituent attach to it. This permanent polarity is due electron displacement due to difference in electronegativities this is called inductive effect or I effect. The inducitve effect depends in the electronegativity of the substituent. The inductive effect is broadly classified as (i) negative inductive effect or -I effect. (ii) positive inductive effect or +I effect. Which of the following statements is correct about inductive effect ?

    Inductive effect refers to

    +I effect (inductive effect) is shown by

    +I effect (inductive effect) is shown by

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