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Consider the basicity of the following a...

Consider the basicity of the following aromatic amines:
(I) aniline `" "`(II) p-nitroaniline `" "`(III) p-methoxyaniline `" "`(IV) p-methylaniline
The correct order of decreasing basicity is:

A

`III gt IV gt I gt II`

B

`III gt IV gt II gt I`

C

`I gt II gt III gt IV`

D

`IV gt III gt II gt I`

Text Solution

Verified by Experts

The correct Answer is:
A
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Knowledge Check

  • Consider the following base (I) o-nitroaniline " " (II) m-nitroaniline " " (III) p-nitroaniline The decreasing order of basicity is:

    A
    `II gt III gt I`
    B
    `II gt I gt III`
    C
    `I gt II gt III`
    D
    `I gt III gt II`

  • Arrange p-methylaniline (I), m-methyl aniline (II), aniline (III), o-methyl aniline (IV), in the order of basicity.

    A
    `I gt II gt III gt IV`
    B
    `IV gt III gt II gt I`
    C
    `II gt I gt III gt IV`
    D
    `I gt III gt II gt IV`

  • Which of the following is the correct decreasing order basicity ?

    A
    `CH_(3)CH_(2)NH_(2) gt HOCH_(2)CH_(2)CH_(2)NH_(2) gt HOCH_(2)CH_(2)NH_(2)`
    B
    `CH_(3)CH_(2)NH_(2) gt HOCH_(2)CH_(2)NH_(2) gt HOCH_(2)CH_(2)CH_(2)NH_(2)`
    C
    `HOCH_(2)CH_(2)CH_(2)NH_(2) gt HOCH_(2)CH_(2)NH_(2) gt CH_(3)CH_(2)NH_(2)`
    D
    `HOCH_(2)CH_(2)NH_(2) gt HOCH_(2)CH_(2)CH_(2)CH_(2)NH_(2) gt CH_(3)CH_(2)NH_(2)`

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