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Assertion : For a first order reaction,t...

Assertion : For a first order reaction,`t_(1//2)` is indepent of rate constant.
Reason : For a first reaction `t_(1//2) prop [R]_(0)`.

A

If both assertion and reason are true and reason is the correct explanation of assertion.

B

If both assertion and reason are true but reason is not the correct explanation of assertion.

C

If assertion is true but reason is false.

D

If both assertion and reason are false.

Text Solution

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The correct Answer is:
To solve the question regarding the assertion and reason related to first-order reactions, we will analyze both statements step by step. ### Step 1: Understanding the Assertion The assertion states that for a first-order reaction, the half-life (\(t_{1/2}\)) is independent of the rate constant. **Analysis**: For a first-order reaction, the half-life is given by the formula: \[ t_{1/2} = \frac{0.693}{k} \] where \(k\) is the rate constant. This indicates that the half-life is inversely proportional to the rate constant \(k\). Therefore, as the rate constant changes, the half-life will also change. **Conclusion**: The assertion is **false**. ### Step 2: Understanding the Reason The reason states that for a first-order reaction, \(t_{1/2}\) is proportional to the initial concentration \([R]_0\). **Analysis**: For a first-order reaction, the half-life is independent of the initial concentration. The half-life remains constant regardless of the concentration of the reactant. The formula for half-life does not include the initial concentration, confirming that it does not depend on \([R]_0\). **Conclusion**: The reason is also **false**. ### Final Conclusion Both the assertion and the reason are false. ### Summary - Assertion: False (Half-life for a first-order reaction is dependent on the rate constant). - Reason: False (Half-life for a first-order reaction is independent of initial concentration).

To solve the question regarding the assertion and reason related to first-order reactions, we will analyze both statements step by step. ### Step 1: Understanding the Assertion The assertion states that for a first-order reaction, the half-life (\(t_{1/2}\)) is independent of the rate constant. **Analysis**: For a first-order reaction, the half-life is given by the formula: \[ ...
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Knowledge Check

  • Rate constant in case of first order reaction is

    A
    inversely proportional to the concentration units
    B
    independent of concentration units
    C
    directly proportional to concentration units
    D
    inversely proportional to the square of concentration units.
  • The value of rate constant of a pseudo first order reaction

    A
    depends on the concentration of reactants present in small amount.
    B
    depends on the concentration of reactants present in excess
    C
    is independent of the concentration of reactants
    D
    depends only on temperature.
  • The value of rate constant of a pseudo first order reaction

    A
    depends on the concentration of reactants present in small amount.
    B
    depends on the concentration of reactants present in excess
    C
    is independent of the concentration of reactants
    D
    depends only on temperature.
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