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Maximum covalency of nitrogen is :...

Maximum covalency of nitrogen is :

A

3

B

5

C

4

D

6

Text Solution

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The correct Answer is:
To determine the maximum covalency of nitrogen, we need to analyze its electronic configuration and bonding capabilities. Here’s a step-by-step solution: ### Step 1: Understand the Electronic Configuration of Nitrogen - Nitrogen (N) has an atomic number of 7. - Its electronic configuration is 1s² 2s² 2p³. - This means nitrogen has a total of 5 valence electrons (2 from 2s and 3 from 2p). **Hint:** Remember that the number of valence electrons determines how many bonds an atom can typically form. ### Step 2: Determine the Maximum Number of Bonds - In general, covalency refers to the number of covalent bonds an atom can form. - Nitrogen can form bonds by sharing its valence electrons with other atoms. - It can form single bonds, double bonds, and in some cases, triple bonds. **Hint:** Think about how nitrogen can share its electrons with other atoms to form different types of bonds. ### Step 3: Analyze Bonding in Nitrogen Compounds - In compounds like ammonia (NH₃), nitrogen forms three single bonds with hydrogen. - In nitrate (NO₃⁻), nitrogen forms one double bond with oxygen and two single bonds with two other oxygen atoms, totaling four bonds. **Hint:** Consider common nitrogen compounds to see how many bonds nitrogen forms in each case. ### Step 4: Consider the Limitations of Nitrogen - Nitrogen does not have d-orbitals available for bonding since it is a second-period element. - Therefore, it cannot expand its octet beyond 8 electrons, which limits its maximum covalency. **Hint:** Recall that only elements in the third period and beyond can utilize d-orbitals to expand their octet. ### Step 5: Conclusion - Based on the analysis, nitrogen can form a maximum of four covalent bonds. - Thus, the maximum covalency of nitrogen is **4**. **Final Answer:** The maximum covalency of nitrogen is **4**.
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Knowledge Check

  • Assertion : The covalence of nitrogen in N_(2)O_(5) is 5 Reason : Nitrogen can expand its covalence beyond 4.

    A
    If both assertion and reason are true and reason is the correct explanation of assertion.
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion.
    C
    If assertion is true but reason is false.
    D
    If both assertion and reason are false.
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