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In disaccharides, if the reducing groups...

In disaccharides, if the reducing groups of monosaccharides, i.e., aldehydic or ketonic groups are bonded, these are non-reducing sugars. Which of the following disaccharide is a non-reducing sugar?

A

B

C

D

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The correct Answer is:
To determine which disaccharide is a non-reducing sugar, we need to understand the concept of reducing and non-reducing sugars based on the presence of free aldehydic or ketonic groups in the monosaccharides that make up the disaccharide. ### Step-by-Step Solution: 1. **Understanding Reducing and Non-Reducing Sugars**: - Reducing sugars are those that have a free aldehyde or ketone group. This allows them to reduce other compounds and participate in redox reactions. - Non-reducing sugars do not have a free aldehyde or ketone group because the reducing groups are involved in glycosidic bonds. 2. **Identifying the Anomeric Carbon**: - In a disaccharide, each monosaccharide has an anomeric carbon, which is the carbon derived from the carbonyl carbon of the monosaccharide. - If the anomeric carbon of either monosaccharide is involved in a glycosidic bond (i.e., it is bonded to another monosaccharide), it cannot act as a reducing sugar. 3. **Analyzing the Given Disaccharides**: - We need to look at the structure of the disaccharides provided in the options and identify the anomeric carbons. - If both anomeric carbons are involved in glycosidic bonds and do not have a free hydroxyl (OH) group, then the disaccharide is non-reducing. 4. **Conclusion**: - After analyzing the structures, we find that the disaccharide that has both anomeric carbons involved in glycosidic bonds, without any free OH group, is classified as a non-reducing sugar. - For example, sucrose is a common non-reducing sugar because both of its anomeric carbons are involved in the glycosidic bond, leaving no free OH group. ### Final Answer: The disaccharide that is a non-reducing sugar is **sucrose**.

To determine which disaccharide is a non-reducing sugar, we need to understand the concept of reducing and non-reducing sugars based on the presence of free aldehydic or ketonic groups in the monosaccharides that make up the disaccharide. ### Step-by-Step Solution: 1. **Understanding Reducing and Non-Reducing Sugars**: - Reducing sugars are those that have a free aldehyde or ketone group. This allows them to reduce other compounds and participate in redox reactions. - Non-reducing sugars do not have a free aldehyde or ketone group because the reducing groups are involved in glycosidic bonds. ...
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Knowledge Check

  • Which is a non-reducing sugar?

    A
    glucose
    B
    sucrose
    C
    galactose
    D
    mannose
  • Non-reducing sugar is

    A
    maltose
    B
    sucrose
    C
    lactose
    D
    none of these.
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