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What will be the products of electrolysi...

What will be the products of electrolysis of `AgNO_(3)` solution in water with platinum electrodes ?

A

Ag is liberated at cathode and Ag is deposited in anode.

B

Ag is liberated at cathode and `O_(2)` is liberated at anode.

C

Ag is liberated at anode and water is liberated at cathode.

D

Ag is liberated at cathode and silver oxide is liberated at anode.

Text Solution

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The correct Answer is:
To determine the products of the electrolysis of an AgNO3 solution in water with platinum electrodes, we can follow these steps: ### Step 1: Dissociation of AgNO3 The first step in the electrolysis process is the dissociation of silver nitrate (AgNO3) in water. This dissociation produces silver ions (Ag⁺) and nitrate ions (NO₃⁻). **Equation:** \[ \text{AgNO}_3 \rightarrow \text{Ag}^+ + \text{NO}_3^- \] ### Step 2: Ionization of Water Water also undergoes self-ionization, producing hydrogen ions (H⁺) and hydroxide ions (OH⁻). **Equation:** \[ \text{H}_2\text{O} \rightarrow \text{H}^+ + \text{OH}^- \] ### Step 3: Reactions at the Electrodes In electrolysis, reactions occur at both the cathode (negative electrode) and the anode (positive electrode). #### At the Cathode: At the cathode, the silver ions (Ag⁺) will gain electrons (reduction) to form solid silver (Ag). **Equation:** \[ \text{Ag}^+ + e^- \rightarrow \text{Ag} \] #### At the Anode: At the anode, water will undergo oxidation, producing oxygen gas (O₂), hydrogen ions (H⁺), and electrons. **Equation:** \[ 2\text{H}_2\text{O} \rightarrow 4\text{H}^+ + \text{O}_2 + 4e^- \] ### Step 4: Summary of Products From the reactions at the electrodes, we can summarize the products of the electrolysis: - At the cathode, solid silver (Ag) is deposited. - At the anode, oxygen gas (O₂) is liberated. ### Final Answer: The products of the electrolysis of AgNO3 solution in water with platinum electrodes are: - **At the Cathode:** Silver (Ag) - **At the Anode:** Oxygen gas (O₂)

To determine the products of the electrolysis of an AgNO3 solution in water with platinum electrodes, we can follow these steps: ### Step 1: Dissociation of AgNO3 The first step in the electrolysis process is the dissociation of silver nitrate (AgNO3) in water. This dissociation produces silver ions (Ag⁺) and nitrate ions (NO₃⁻). **Equation:** \[ \text{AgNO}_3 \rightarrow \text{Ag}^+ + \text{NO}_3^- \] ...
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Knowledge Check

  • What wil be the products of electrolysis of an aqueous solution of AgNO_(3) with silver electrodes ?

    A
    Ag from Ag anode dissolves while `Ag^(+)` from solution gets deposited on cathode.
    B
    Ag is liberated at cathode and `O_(2)` is liberated at anode.
    C
    Ag at cathode and nitric acid at anode is liberated.
    D
    No reaction takes place.
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