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The equilibrium constant at 717 K for th...

The equilibrium constant at 717 K for the reaction: `H_(2(g))+I_(2(g))lArr2HI_((g))` is 50.
The equilibrium constant for the reaction:
`2HI_(2(g))lArrH_(2(g))+I_(2(g))` is

A

0.5

B

`2xx10^(-2)`

C

`4.0`

D

`1xx10^(-1)`

Text Solution

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The correct Answer is:
To find the equilibrium constant for the reaction \( 2HI_{(g)} \rightleftharpoons H_{2(g)} + I_{2(g)} \), we can use the relationship between the equilibrium constants of forward and reverse reactions. ### Step-by-Step Solution: 1. **Identify the given reaction and its equilibrium constant**: The equilibrium constant \( K \) for the reaction: \[ H_{2(g)} + I_{2(g)} \rightleftharpoons 2HI_{(g)} \] is given as \( K = 50 \) at 717 K. 2. **Write the expression for the equilibrium constant**: For the forward reaction, the equilibrium constant \( K \) can be expressed as: \[ K = \frac{[HI]^2}{[H_2][I_2]} \] where \( [HI] \), \( [H_2] \), and \( [I_2] \) are the equilibrium concentrations of hydrogen iodide, hydrogen, and iodine, respectively. 3. **Determine the equilibrium constant for the reverse reaction**: The reverse reaction is: \[ 2HI_{(g)} \rightleftharpoons H_{2(g)} + I_{2(g)} \] The equilibrium constant for the reverse reaction, which we will denote as \( K' \), is related to \( K \) by the following relationship: \[ K' = \frac{1}{K} \] 4. **Calculate \( K' \)**: Substituting the value of \( K \): \[ K' = \frac{1}{50} = 0.02 \] 5. **Final Answer**: The equilibrium constant for the reaction \( 2HI_{(g)} \rightleftharpoons H_{2(g)} + I_{2(g)} \) is: \[ K' = 0.02 \]
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