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Aqueous solution of sodium acetate is...

Aqueous solution of sodium acetate is

A

Alkaline

B

Neutral

C

Weakly acidic

D

Strongly acidic

Text Solution

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The correct Answer is:
To determine the nature of an aqueous solution of sodium acetate, we can follow these steps: ### Step 1: Identify the components of sodium acetate Sodium acetate (CH₃COONa) is a salt formed from the reaction of acetic acid (CH₃COOH), a weak acid, and sodium hydroxide (NaOH), a strong base. ### Step 2: Understand the nature of the ions in solution When sodium acetate is dissolved in water, it dissociates into sodium ions (Na⁺) and acetate ions (CH₃COO⁻). - Na⁺ is a spectator ion and does not affect the pH of the solution. - CH₃COO⁻, being the conjugate base of the weak acid acetic acid, can accept protons (H⁺) from water, leading to an increase in hydroxide ions (OH⁻) in the solution. ### Step 3: Analyze the effect on pH The acetate ion (CH₃COO⁻) will react with water in a hydrolysis reaction: \[ \text{CH}_3\text{COO}^- + \text{H}_2\text{O} \rightleftharpoons \text{CH}_3\text{COOH} + \text{OH}^- \] This reaction produces hydroxide ions (OH⁻), which increases the pH of the solution. ### Step 4: Determine the pH of the solution Since the solution contains a weak acid's conjugate base (acetate ion), the pH can be calculated using the formula for the pH of a salt derived from a weak acid and a strong base: \[ \text{pH} = 7 + \frac{1}{2} \text{pK}_a + \frac{1}{2} \log C \] Where: - \( \text{pK}_a \) is the negative logarithm of the acid dissociation constant of acetic acid. - \( C \) is the concentration of the sodium acetate solution. This formula indicates that the pH will be greater than 7. ### Step 5: Conclusion Since the pH of the solution is greater than 7, we conclude that an aqueous solution of sodium acetate is basic (alkaline). ### Final Answer An aqueous solution of sodium acetate is basic (alkaline). ---
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Knowledge Check

  • The aqueous solution of sodium acetate with minimum pH is

    A
    `0.01 M`
    B
    `0.001 M`
    C
    `0.0001 M`
    D
    `0.1 M`
  • The hydrolysis constang of 0.1M aqueous solution of sodium acetate if K_(a) of CH_(3)COOH = 1.8 xx 10^(-5) is

    A
    `5.5 xx 10^(-10)`
    B
    `4.5 xx 10^(-8)`
    C
    `5.5 xx 10^(-12)`
    D
    None of these
  • Aqueous solution of sodium acetane and sodium propionate on electrolysis yields :

    A
    ehtane
    B
    butane
    C
    propane
    D
    all of these
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