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From the rate expression for the followi...

From the rate expression for the following reactions, determine their order of reaction and the dimensions of the rate constants:
(i) `3NO(g) to N_(2)O(g), "Rate"=k[NO]^(2)`
(ii) `H_(2)O_(2)(aq)+3I^(-)(aq)+2H^(+) to 2H_(2)O(l)+I_(3)^(-), "Rate"=k[H_(2)O_(2)][I^(-)]`
(iii) `CH_(3)CHO(g) to CH_(4)(g)+CO(g) , "Rate"=k[CH_(3)CHO]^(3//2)`
(iv) `C_(2)H_(5)Cl(g) to C_(2)H_(4)(g)+HCl (g) , "Rate"=k[C_(2)H_(5)Cl]`

Text Solution

Verified by Experts

(i) Order = 2, Dimensions of `k=("Rate")/([NO]^(2))=("mol L"^(-1)s^(-1))/(("mol L"^(-1))^(2))="L mol"^(-1)s^(-1)`
(ii) Order = 2, Dimensions of k = Same as in (i)
(iii) Order `=(3)/(2)`, Dimensions of `k=("Rate")/([CH_(3)CHO]^(3//2))=("mol L"^(-1)s^(-1))/(("mol L"^(-1))^(3//2))=L^(1//2)"mol"^(-1//2)s^(-1)`
(iv) Order = 1, Dimensions of `k=("Rate")/([C_(2)H_(5)Cl])=("mol L"^(-1)s^(-1))/("mol L"^(-1))=s^(-1)`.
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From the rate expression for the following reactions determines the order of reaction and the dimensions of the rate constant. a) 3NO(g) to N_(2)O(g) + NO_(2)(g) , Rate =k[NO]^(2) b) H_(2)O_(2)(aq) + 3I^(-)(aq) + 2H^(+)(aq) to 2H_(2)O(l) + I_(3)^(-) , Rate = [H_(2)O_(2)][I^(-)] c) CH_(3)CHO(g) to CH_(4)(g) + CO(g) : Rate = k[CH_(3)CHO]^(3//2) d) CHCl_(3)(g) to Cl_(4)(g) + HCl(g) : Rate = k[CHCl_(3)][Cl_(2)]^(1//2) e) C_(2)H_(5)Cl(g) to C_(2)H_(4)(g) + HCl(g) , Rate = k[C_(2)H_(5)Cl]

From the rater expression for the following reactions, determine their order of reaction and dimensions of the rate constants. a. 3NO(g) rarr N_(2)O(g), Rate =k[NO]^(2) b. H_(2)O_(2)(aq)+3I^(c-)(aq)+2H^(o+) rarr 2H_(2)O(l)+I_(3)^(c-), Rate =k[H_(2)O_(2)][I^(c-)] c. CH_(3)CHO(g)rarr CH_(4)(g)+CO(g), Rate =k[CH_(3)CHO]^(3//2) d. C_(2)H_(5)Cl(g) rarr C_(2)H_(4)(g)+HCl(g), Rate k[C_(2)H_(5)Cl]

From the expression of the following reactions, determine order of reaction and the dimensions of the rate constant. (i) 3NO(g)rarrN_2O(g)+NO_2(g) " Rate"=k[NO]^2 (ii) H_2O_2(aq)+3l^(-)(aq)+2H^+rarr2H_2O(l)+l_3^(-)" Rate"= k[H_2O_2][l] (iii) CH_3CHO(g) rarrCH_4(g)+CO(g)+CO(g)" Rate" =k[CH_3CHO]^(3//2) (iv) C_2H_5Cl(g)rarrC_2H_4(g)+HCl(g)" Rate"=k[C_2H_5Cl]

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Find overall order of reaction if rate law expression are as follows:- (a) rate =K[CO]^(2)[Cl_(2)]^(0.5) (ii) rate =K[CH_(3)COOC_(2)H_(5)]^(1)[H_(2)O]^(0)

Determine which of the following reactions at constant pressure represents surroundings that do work on the system: I. 4NH_(3)(g)+7O_(2)(g)rarr4NO_(2)(g)+6H_(2)O(g) II. CO(g)+2H_(2)(g)rarrCH_(3)OH(l) III. C(s,"graphite")+H_(2)O(g)rarrCO(g)+H_(2)(g) IV. H_(2)OrarrH_(2)O(l)

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