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(a) Explain the following terms: (i) R...

(a) Explain the following terms:
(i) Rate of a reaction. (ii) Activation energy of a reaction.
(b)The decomposition of phosphine, `PH_(3)` proceeds according to the following equation:
Rate `=k[PH_(3)]`
The half-life of `PH_(3)` is 37.9 s at `120^(@)C`.
(i) How much time is required for `3//4th` of `PH_(3)` to decompose?
(ii) What fraction of the original sample of `PH_(3)` remains behind after 1 minute?

Text Solution

Verified by Experts

The correct Answer is:
(i) 75.83s, (ii) 0.3342
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Knowledge Check

  • The decomposition of phosphine (PH_(3)) on tungsten at low pressure is a first-orfer reaction . It is because the

    A
    Rate of decomposition is very slow
    B
    Rate is proportional to the surface coverage
    C
    Rate is inversely proportional to the surface coverage
    D
    Rate is independent of the surface coverage
  • The decomposition of phosphine (PH_3) on tangents at low pressure is a first-order reaction. It is because the:

    A
    Rate is proportional to the surface coverage
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    Rate is independent of the surface coverage
    D
    Rate of decomposition is very low
  • The decomposition of phosphine (PH_3) on tangents at low pressure is a first-order reaction. It is because the:

    A
    Rate is proportional to the surface coverage
    B
    Rate is inversely proportional to the surface coverage
    C
    Rate is independent of the surface coverage
    D
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