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Which of the following aqueous solutions...

Which of the following aqueous solutions remain alkaline after electrolysis ?

A

`CH_(3)COONa`

B

`KNO_(3)`

C

`NaCl`

D

`LiF`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which aqueous solutions remain alkaline after electrolysis, we will analyze each option step by step. ### Step 1: Analyze CH3COONa (Sodium Acetate) - **Electrolysis Reaction**: - At the cathode, water is reduced to form hydroxide ions (OH⁻) and hydrogen gas (H₂). - At the anode, the acetate ion (CH₃COO⁻) is oxidized, producing ethene (C₂H₄) and carbon dioxide (CO₂). - **Result**: The production of hydroxide ions makes the solution basic. ### Step 2: Analyze KNO3 (Potassium Nitrate) - **Electrolysis Reaction**: - At the cathode, water is again reduced to form hydroxide ions (OH⁻) and hydrogen gas (H₂). - At the anode, water is oxidized to produce oxygen gas (O₂) and hydrogen ions (H⁺). - **Result**: The hydroxide ions (OH⁻) produced at the cathode will neutralize the hydrogen ions (H⁺) produced at the anode, resulting in a neutral solution (pH = 7). ### Step 3: Analyze NaCl (Sodium Chloride) - **Electrolysis Reaction**: - At the cathode, water is reduced to form hydroxide ions (OH⁻) and hydrogen gas (H₂). - At the anode, chloride ions (Cl⁻) are oxidized to produce chlorine gas (Cl₂). - **Result**: The production of hydroxide ions makes the solution basic. ### Step 4: Analyze LiF (Lithium Fluoride) - **Electrolysis Reaction**: - At the cathode, water is reduced to form hydroxide ions (OH⁻) and hydrogen gas (H₂). - At the anode, water is oxidized to produce oxygen gas (O₂) and hydrogen ions (H⁺). - **Result**: The hydroxide ions (OH⁻) produced at the cathode will neutralize the hydrogen ions (H⁺) produced at the anode, resulting in a neutral solution (pH = 7). ### Conclusion From the analysis: - **CH3COONa** and **NaCl** remain alkaline after electrolysis due to the production of hydroxide ions. - **KNO3** and **LiF** result in neutral solutions after electrolysis. ### Final Answer The aqueous solutions that remain alkaline after electrolysis are: - **CH3COONa (Sodium Acetate)** - **NaCl (Sodium Chloride)**

To determine which aqueous solutions remain alkaline after electrolysis, we will analyze each option step by step. ### Step 1: Analyze CH3COONa (Sodium Acetate) - **Electrolysis Reaction**: - At the cathode, water is reduced to form hydroxide ions (OH⁻) and hydrogen gas (H₂). - At the anode, the acetate ion (CH₃COO⁻) is oxidized, producing ethene (C₂H₄) and carbon dioxide (CO₂). - **Result**: The production of hydroxide ions makes the solution basic. ...
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