Home
Class 12
CHEMISTRY
Define Equivalent conductivity....

Define Equivalent conductivity.

Text Solution

AI Generated Solution

The correct Answer is:
**Step-by-Step Text Solution:** 1. **Definition of Equivalent Conductivity**: Equivalent conductivity is defined as the conducting power of all the ions in a solution when 1 gram equivalent of an electrolyte is dissolved in it. 2. **Understanding Conducting Power**: The conducting power refers to the ability of ions to conduct electricity in a solution. When an electrolyte dissolves, it dissociates into its constituent ions, which are responsible for conducting electrical current. 3. **Relation to Specific Conductivity**: Equivalent conductivity is related to specific conductivity (also known as conductivity) of the solution. Specific conductivity measures how well a solution can conduct electricity, while equivalent conductivity takes into account the amount of electrolyte present. 4. **Mathematical Representation**: Equivalent conductivity (Λ) can be mathematically expressed as: \[ \Lambda = \frac{\kappa}{C} \] where \( \kappa \) is the specific conductivity of the solution and \( C \) is the concentration of the electrolyte in gram equivalents per liter. 5. **Units of Equivalent Conductivity**: The unit of equivalent conductivity is typically expressed in S m²/mol (Siemens meter squared per mole) or S cm²/eq (Siemens centimeter squared per equivalent). 6. **Importance in Electrochemistry**: Equivalent conductivity is an important parameter in electrochemistry as it helps in understanding the behavior of electrolytes in solution, their dissociation, and their ability to conduct electricity.
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exerciseinterger|8 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercisefill In The Blanks|25 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Ingle Correct|178 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|29 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives (Subjective)|14 Videos

Similar Questions

Explore conceptually related problems

The increase in equivalent conductivity of a weak electrolyte with dilution is due to :

If the specific conductance of 1 M H_(2)SO_(4) solution is 26xx10^(-2)S cm^(2) , then the equivalent conductivity would be

Ionic conductance of H^(+) and SO_(4) are x and yS cm^(2) mol^(-1) . Hence equivalent conductivity of H_(2)SO_(4) is

Define the following terms : Equivalent conductivity

Conductivity of 0.12 M CuSO_(4) solution at 298 K is 1.8 xx 10^(-2) S cm^(-1) Calculate its equivalent conductivity

Which of the following correctly represent the equivalent conductivity (^^_(N)) and molar conductivity (^^_(M)) of aluminium sulphate where equivalent conductivities of Al^(+3) and SO_(4)^(-2) are lamda_(1) and lamda_(2) respectively?

The limiting equivalent conductivity of NaCl, KCl and KBr are 126.5,150.0 and 151.5 S cm^(2) eq^(-1) , respectively. The limiting equivalent ionic conductance for Br^(-) is 78 S cm^(2) eq^(-1) . The limiting equivalent ionic conductance for Na^(+) ions would be :

The limiting equivalent conductivity of NaCl, KCl and KBr are 126.5,150.0 and 151.5 S cm^(2) eq^(-1) , respectively. The limiting equivalent ionic conductance for Br^(-) is 78 S cm^(2) eq^(-1) . The limiting equivalent ionic conductance for Na^(+) ions would be :

It is practically difficult to calculate the equivalent conductivity of a weak electrolyte in aqueous solution. Comment.

Select the equivalent conductivity of 1.0 M H_(2)SO_(4) , if its conductivity is 0.26 ohm^(-1) cm^(-1) :

CENGAGE CHEMISTRY ENGLISH-ELECTROCHEMISTRY-Exerciseassertion -Reasoning
  1. Assertion (A): 1 Faraday of electricity deposits 1 g equivalent of Ag ...

    Text Solution

    |

  2. Assertion (A): The mobility of Na^(o+) is lower than that of K^(o+) io...

    Text Solution

    |

  3. Define Equivalent conductivity.

    Text Solution

    |

  4. Assertion (A): wedge(m(H^(o+))) and wedge(m(overset(c)(O)H)) ions are ...

    Text Solution

    |

  5. Assertion (A): Ionic conductivities increase with increase of temperat...

    Text Solution

    |

  6. Assertion (A: Cell constant is the EMF of a cell. Reason (R): Cell c...

    Text Solution

    |

  7. Assertion (A): At the end of electrolysis using Pt electrodes, an aque...

    Text Solution

    |

  8. Assertion (A): Cu liberates H(2)(g) from a dilute solution of HCl. R...

    Text Solution

    |

  9. Assertion(A): Na^(o+) ions are discharged in preference to H^(o+) ions...

    Text Solution

    |

  10. Assertion (A) : Cu gets readily corroded in acidic aqueous solution. ...

    Text Solution

    |

  11. Assertion (A) : Galvanized iron is protected from Rusting. Reason (...

    Text Solution

    |

  12. A Daniell cell : Zn|Zn^(2+)||Cu^(2+)|Cu with E(cell)=1.1V is given. ...

    Text Solution

    |

  13. Assertion (A): The electrolysis of NaCl solution gives H(2)(g) at cath...

    Text Solution

    |

  14. Assertion (A) : Fe is protected from corrosing by connecting Mg metal ...

    Text Solution

    |

  15. Assertion (A) : The Daniell cell becomes dead after sometimes. Reaso...

    Text Solution

    |

  16. Assertion (A): wedge^(@).(eq(CH(3)COOH)) cannote be determines experim...

    Text Solution

    |

  17. Assertion (A) : The presence of CO(2) in the air accelerates corrosio...

    Text Solution

    |

  18. Assertion (A) : (H(2)+O(2)) fuel cell gives a constant voltages throug...

    Text Solution

    |

  19. Assertion (A) : In a Daniell cell, if the concentration of Cu^(2+) an...

    Text Solution

    |

  20. Assertion (A) : The ratio of specific conductivity to the observed co...

    Text Solution

    |