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The rate constant for zero order reactio...

The rate constant for zero order reaction is

A

`A. k = (c_(0))/(2t)`

B

`B..k = ((c_(0)-c_(t)))/(t)`

C

`C. k = ln((c_(0)-c_(t))/(2t))`

D

`D. k = (c_(0))/(c_(t))`

Text Solution

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The correct Answer is:
To determine the rate constant for a zero-order reaction, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Zero-Order Reaction**: In a zero-order reaction, the rate of reaction is constant and does not depend on the concentration of the reactants. This means that the rate of reaction can be expressed as: \[ \text{Rate} = k \] where \( k \) is the rate constant. 2. **Write the Integrated Rate Law**: For a zero-order reaction, the integrated rate law can be expressed as: \[ [C_0] - [C_t] = kt \] where: - \( [C_0] \) is the initial concentration of the reactant, - \( [C_t] \) is the concentration of the reactant at time \( t \), - \( k \) is the rate constant, - \( t \) is the time. 3. **Rearranging the Equation**: We can rearrange the integrated rate law to solve for the rate constant \( k \): \[ k = \frac{[C_0] - [C_t]}{t} \] 4. **Conclusion**: Thus, the expression for the rate constant \( k \) for a zero-order reaction is: \[ k = \frac{[C_0] - [C_t]}{t} \] ### Final Answer: The rate constant for a zero-order reaction is given by the formula: \[ k = \frac{[C_0] - [C_t]}{t} \]

To determine the rate constant for a zero-order reaction, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Zero-Order Reaction**: In a zero-order reaction, the rate of reaction is constant and does not depend on the concentration of the reactants. This means that the rate of reaction can be expressed as: \[ \text{Rate} = k ...
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The order of reaction is an experimentally determined quanity. It may be zero, poistive, negative, or fractional. The kinetic equation of nth order reaction is k xx t = (1)/((n-1))[(1)/((a-x)^(n-1)) - (1)/(a^(n-1))] …(i) Half life of nth order reaction depends on the initial concentration according to the following relation: t_(1//2) prop (1)/(a^(n-1)) ...(ii) The unit of the rate constant varies with the order but general relation for the unit of nth order reaction is Units of k = [(1)/(Conc)]^(n-1) xx "Time"^(-1) ...(iii) The differential rate law for nth order reaction may be given as: (dX)/(dt) = k[A]^(n) ...(iv) where A denotes the reactant. The rate constant for zero order reaction is where c_(0) and c_(t) are concentration of reactants at respective times.

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