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Which of the following will not be able ...

Which of the following will not be able to show optical isomerism (enantiomerism)?

A

`1,2`-Propadiene

B

`2,3`-Pentadiene

C

sec-Butyl alcohol

D

All exhibit enantiomerism

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds will not be able to show optical isomerism (enantiomerism), we will analyze each option step by step. ### Step 1: Analyze 1,2-Propadiene 1,2-Propadiene has the structure: \[ \text{CH}_2=\text{C}=\text{CH}_2 \] In this molecule, the terminal carbon atoms each have two hydrogen atoms attached. Therefore, there is a plane of symmetry present in the molecule. Since it contains a plane of symmetry, it cannot show optical isomerism. ### Step 2: Analyze 2,3-Pentadiene 2,3-Pentadiene has the structure: \[ \text{CH}_3-\text{CH}=\text{C}=\text{CH}-\text{CH}_3 \] In this structure, the second and third carbon atoms have different groups attached (one has a hydrogen and the other has a methyl group). There is no plane of symmetry present in this molecule, which allows it to show optical isomerism. ### Step 3: Analyze Secondary Butyl Alcohol Secondary butyl alcohol has the structure: \[ \text{CH}_3-\text{CH(OH)}-\text{CH}_2-\text{CH}_3 \] The second carbon (the one with the hydroxyl group) is a chiral center because it is attached to four different groups (methyl, hydroxyl, hydrogen, and ethyl). Therefore, this compound can show optical isomerism. ### Conclusion From the analysis: - 1,2-Propadiene **cannot** show optical isomerism due to the presence of a plane of symmetry. - 2,3-Pentadiene **can** show optical isomerism. - Secondary butyl alcohol **can** show optical isomerism. Thus, the compound that will not be able to show optical isomerism is **1,2-Propadiene**. ### Final Answer The correct answer is **Option 1: 1,2-Propadiene**. ---

To determine which of the given compounds will not be able to show optical isomerism (enantiomerism), we will analyze each option step by step. ### Step 1: Analyze 1,2-Propadiene 1,2-Propadiene has the structure: \[ \text{CH}_2=\text{C}=\text{CH}_2 \] In this molecule, the terminal carbon atoms each have two hydrogen atoms attached. Therefore, there is a plane of symmetry present in the molecule. Since it contains a plane of symmetry, it cannot show optical isomerism. ### Step 2: Analyze 2,3-Pentadiene ...
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Knowledge Check

  • Which of the following will not show geometrical isomerism ?

    A
    `CH_3-underset(CH_3)underset(|)(C)=CH-CH_2-CH_3`
    B
    `CH_3-underset(CH_3)underset(|)(CH)-CH=CH-CH_2-CH_3`
    C
    `CH_3-CH=CH-CH_3`
    D
    `CH_3-CH_2=CH-CH_2-CH_3`
  • Which of the following will not show geometrical isomerism?

    A
    B
    C
    D
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