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Which of the following compounds exhibit...

Which of the following compounds exhibits stereoisomerism?

A

`2`-Methylbutane

B

`3`- Methylbutane

C

`3`-Methylbutanoic acid

D

`2`-Methylbutanoic acid

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The correct Answer is:
To determine which of the given compounds exhibits stereoisomerism, we will analyze each compound step by step. ### Step 1: Understand Stereoisomerism Stereoisomerism refers to compounds that have the same molecular formula and connectivity of atoms but differ in the spatial arrangement of those atoms. This can include geometrical isomerism (cis/trans) and optical isomerism (enantiomers). ### Step 2: Analyze Each Compound 1. **2-Methylbutane**: - Structure: CH3-CH(CH3)-CH2-CH3 - Analysis: This compound does not have a double bond or a ring structure, which means it cannot exhibit geometrical isomerism. Additionally, it does not have any chiral carbon (a carbon atom bonded to four different groups), so it cannot exhibit optical isomerism. - Conclusion: **Does not exhibit stereoisomerism.** 2. **3-Methylbutane**: - Structure: CH3-CH2-CH(CH3)-CH3 - Analysis: Similar to 2-methylbutane, this compound does not have a double bond or ring structure, and it also lacks a chiral carbon. - Conclusion: **Does not exhibit stereoisomerism.** 3. **3-Methylbutanoic Acid**: - Structure: CH3-CH(CH3)-CH2-COOH - Analysis: This compound has a carboxylic acid group but still does not have a chiral carbon because the carbon at position 3 is attached to two identical methyl groups. - Conclusion: **Does not exhibit stereoisomerism.** 4. **2-Methylbutanoic Acid**: - Structure: CH3-CH(CH3)-CH2-COOH - Analysis: In this compound, the carbon at position 2 is chiral because it is bonded to four different groups: a carboxylic acid (COOH), a methyl group (CH3), a hydrogen atom (H), and an ethyl group (CH2-CH3). Therefore, this compound can exhibit optical isomerism. - Conclusion: **Exhibits stereoisomerism.** ### Final Conclusion Among the given compounds, only **2-Methylbutanoic Acid** exhibits stereoisomerism due to the presence of a chiral carbon atom.

To determine which of the given compounds exhibits stereoisomerism, we will analyze each compound step by step. ### Step 1: Understand Stereoisomerism Stereoisomerism refers to compounds that have the same molecular formula and connectivity of atoms but differ in the spatial arrangement of those atoms. This can include geometrical isomerism (cis/trans) and optical isomerism (enantiomers). ### Step 2: Analyze Each Compound 1. **2-Methylbutane**: - Structure: CH3-CH(CH3)-CH2-CH3 ...
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CENGAGE CHEMISTRY ENGLISH-ISOMERISM-Single correct answer type (Exercise)
  1. An S(N)2 reaction at an asymmetric carbon of a compound always g...

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  2. The nodal plane in the pi -bond of ethene is located in :

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  3. Which of the following compounds exhibits stereoisomerism?

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  4. Consider the following reaction CH(3)-underset(D)underset(CH)-unders...

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  5. Which of the following hydrocarbons has the lowest dipole moment?

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  6. The geometrical isomerism is shown by:

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  7. The number of geometrical isomers in CH(3)CH=N-OH is

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  8. The smallest aldehyde and its next homologue are treated with NH(2)OH ...

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  9. What are the numerical values of N and M?

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  10. Molecule in which the distance between two adjacent carbon atom is lar...

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  11. The compound which is not isomeric with diethyl ether is:

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  12. Among the following, the compound that can be most readily sulphonated...

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  13. Which of the following compounds will exhibit cis-trans (geometrical) ...

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  14. An isomer of ethanol is:

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  15. Which of the following will have the least hindered rotation about car...

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  16. The number of isomers of C(6)H(14) is:

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  17. The enolic form of acetone contains:

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  18. Three dimensional arrangements which ca be interconverted into one ano...

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  19. How many optically active stereoisomers are possible for butane-2, 3-d...

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  20. The optically active tartaric acid is named as D-(+)- tartaric acid be...

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