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Which of the following compounds exhibit...

Which of the following compounds exhibits stereoisomerism?

A

`2`-Methyl butene

B

`3`-Methyl butyne

C

`3`-Methyl butanoic acid

D

`2`-Methyl butanoic acid

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds exhibits stereoisomerism, we need to follow these steps: ### Step 1: Understand Stereoisomerism Stereoisomerism occurs when compounds have the same connectivity of atoms but differ in the spatial arrangement of those atoms. This can lead to different physical and chemical properties. **Hint:** Remember that stereoisomers include enantiomers and diastereomers, which arise from chiral centers or geometric arrangements. ### Step 2: Identify Chiral Centers A chiral center (or chiral carbon) is a carbon atom that is attached to four different groups. The presence of at least one chiral center in a compound typically indicates that it can exhibit stereoisomerism. **Hint:** Look for carbon atoms that have four different substituents attached to them. ### Step 3: Analyze the Given Compounds Let’s analyze the given compound, 2-methylbutanoic acid: - The structure of 2-methylbutanoic acid can be drawn to identify any chiral centers. - Upon drawing, we find that the second carbon in the chain has four different groups attached (a methyl group, a carboxylic acid group, a hydrogen, and the rest of the carbon chain). **Hint:** When drawing the structure, label each substituent clearly to see if they are all different. ### Step 4: Confirm the Existence of Stereoisomers Since 2-methylbutanoic acid has a chiral center, it can exist as two enantiomers (S and R configurations). This confirms that it exhibits stereoisomerism. **Hint:** Remember that each chiral center can lead to two configurations (R and S), which are mirror images of each other. ### Step 5: Conclusion Based on the analysis, 2-methylbutanoic acid is the compound that exhibits stereoisomerism due to the presence of a chiral carbon. **Final Answer:** The correct option for the compound that exhibits stereoisomerism is **2-methylbutanoic acid**.

To determine which of the given compounds exhibits stereoisomerism, we need to follow these steps: ### Step 1: Understand Stereoisomerism Stereoisomerism occurs when compounds have the same connectivity of atoms but differ in the spatial arrangement of those atoms. This can lead to different physical and chemical properties. **Hint:** Remember that stereoisomers include enantiomers and diastereomers, which arise from chiral centers or geometric arrangements. ### Step 2: Identify Chiral Centers ...
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Knowledge Check

  • Which of the following compounds exhibits linkage isomerism?

    A
    `[Co(en)_(3)]Cl_(3)`
    B
    `[Co(NH_(3))_(6)] [Cr(en)_(3)]`
    C
    `[Co(en)_(2)(NO_(2))Cl]Br`
    D
    `[Co(NH_(3))_(5)Cl]Br_(2)`
  • Which of the following compounds exhibit optical isomerism?

    A
    B
    `H_(2)C=C=CH_(2)`
    C
    D
  • Which of the following compounds can exhibit tautomerism?

    A
    `C_(6)H_(5)CHO`
    B
    `C_(6)H_(5)- overset(O) overset(||)(C)-CMe_(3)`
    C
    `C_(6)H_(5)- overset(O) overset(||)(C)-CH_(2)- overset(O) overset(||)(C)-H`
    D
    `C_(6)H_(5)- overset(O) overset(||)(C)-C_(6)H_(5)`
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