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Which of the following compounds exhibit...

Which of the following compounds exhibits stereoisomerism?

A

`2`-Methyl butene

B

`3`-Methyl butyne

C

`3`-Methyl butanoic acid

D

`2`-Methyl butanoic acid

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The correct Answer is:
To determine which of the given compounds exhibits stereoisomerism, we need to follow these steps: ### Step 1: Understand Stereoisomerism Stereoisomerism occurs when compounds have the same connectivity of atoms but differ in the spatial arrangement of those atoms. This can lead to different physical and chemical properties. **Hint:** Remember that stereoisomers include enantiomers and diastereomers, which arise from chiral centers or geometric arrangements. ### Step 2: Identify Chiral Centers A chiral center (or chiral carbon) is a carbon atom that is attached to four different groups. The presence of at least one chiral center in a compound typically indicates that it can exhibit stereoisomerism. **Hint:** Look for carbon atoms that have four different substituents attached to them. ### Step 3: Analyze the Given Compounds Let’s analyze the given compound, 2-methylbutanoic acid: - The structure of 2-methylbutanoic acid can be drawn to identify any chiral centers. - Upon drawing, we find that the second carbon in the chain has four different groups attached (a methyl group, a carboxylic acid group, a hydrogen, and the rest of the carbon chain). **Hint:** When drawing the structure, label each substituent clearly to see if they are all different. ### Step 4: Confirm the Existence of Stereoisomers Since 2-methylbutanoic acid has a chiral center, it can exist as two enantiomers (S and R configurations). This confirms that it exhibits stereoisomerism. **Hint:** Remember that each chiral center can lead to two configurations (R and S), which are mirror images of each other. ### Step 5: Conclusion Based on the analysis, 2-methylbutanoic acid is the compound that exhibits stereoisomerism due to the presence of a chiral carbon. **Final Answer:** The correct option for the compound that exhibits stereoisomerism is **2-methylbutanoic acid**.

To determine which of the given compounds exhibits stereoisomerism, we need to follow these steps: ### Step 1: Understand Stereoisomerism Stereoisomerism occurs when compounds have the same connectivity of atoms but differ in the spatial arrangement of those atoms. This can lead to different physical and chemical properties. **Hint:** Remember that stereoisomers include enantiomers and diastereomers, which arise from chiral centers or geometric arrangements. ### Step 2: Identify Chiral Centers ...
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CENGAGE CHEMISTRY ENGLISH-ISOMERISM-Single correct answer type (Exercise)
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  2. The geometrical isomerism is shown by:

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  3. The number of geometrical isomers in CH(3)CH=N-OH is

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  4. The smallest aldehyde and its next homologue are treated with NH(2)OH ...

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  5. What are the numerical values of N and M?

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  6. Molecule in which the distance between two adjacent carbon atom is lar...

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  7. The compound which is not isomeric with diethyl ether is:

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  8. Among the following, the compound that can be most readily sulphonated...

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  9. Which of the following compounds will exhibit cis-trans (geometrical) ...

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  10. An isomer of ethanol is:

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  11. Which of the following will have the least hindered rotation about car...

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  12. The number of isomers of C(6)H(14) is:

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  13. The enolic form of acetone contains:

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  14. Three dimensional arrangements which ca be interconverted into one ano...

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  15. How many optically active stereoisomers are possible for butane-2, 3-d...

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  16. The optically active tartaric acid is named as D-(+)- tartaric acid be...

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  17. Which of the following compounds will exhibit geometrical isomerism ?

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  18. The number of isomers of the compound C(2)FClBrl is :

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  19. Which of the following compounds exhibits stereoisomerism?

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  20. In the above compound, C(2) is rotated clockwise 120^(@) about C(2)-C(...

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