Home
Class 11
CHEMISTRY
Which of the folowing have identical bon...

Which of the folowing have identical bond orders ? .

A

`O_(2)^(Θ)`

B

`CN^(Θ)`

C

`NO^(o+)`

D

`CN^(o+)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given options have identical bond orders, we need to calculate the total number of electrons for each species and then use that information to find the bond order. The bond order can be calculated using the formula: \[ \text{Bond Order} = \frac{(\text{Number of bonding electrons} - \text{Number of antibonding electrons})}{2} \] However, since we are only interested in identifying which species have the same bond order, we can focus on counting the total number of electrons in each species. ### Step-by-Step Solution: 1. **Identify the first species: O2-** - Each oxygen atom has 8 electrons. - For 2 oxygen atoms: \( 8 \times 2 = 16 \) electrons. - Since there is a negative charge (O2-), we add 1 electron. - Total electrons = \( 16 + 1 = 17 \) electrons. 2. **Identify the second species: CN-** - Carbon has 6 electrons and nitrogen has 7 electrons. - Total from carbon and nitrogen: \( 6 + 7 = 13 \) electrons. - Since there is a negative charge (CN-), we add 1 electron. - Total electrons = \( 13 + 1 = 14 \) electrons. 3. **Identify the third species: NO+** - Nitrogen has 7 electrons and oxygen has 8 electrons. - Total from nitrogen and oxygen: \( 7 + 8 = 15 \) electrons. - Since there is a positive charge (NO+), we subtract 1 electron. - Total electrons = \( 15 - 1 = 14 \) electrons. 4. **Identify the fourth species: CN+** - Carbon has 6 electrons and nitrogen has 7 electrons. - Total from carbon and nitrogen: \( 6 + 7 = 13 \) electrons. - Since there is a positive charge (CN+), we subtract 1 electron. - Total electrons = \( 13 - 1 = 12 \) electrons. 5. **Compare the total number of electrons:** - O2- has 17 electrons. - CN- has 14 electrons. - NO+ has 14 electrons. - CN+ has 12 electrons. 6. **Conclusion:** - CN- and NO+ both have 14 electrons, indicating they have the same bond order. - Therefore, the species with identical bond orders are **CN- and NO+**. ### Final Answer: The species that have identical bond orders are **B (CN-) and C (NO+)**.

To determine which of the given options have identical bond orders, we need to calculate the total number of electrons for each species and then use that information to find the bond order. The bond order can be calculated using the formula: \[ \text{Bond Order} = \frac{(\text{Number of bonding electrons} - \text{Number of antibonding electrons})}{2} \] However, since we are only interested in identifying which species have the same bond order, we can focus on counting the total number of electrons in each species. ### Step-by-Step Solution: ...
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Multiple Correct (Miscellaneous)|10 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Single Correct (Chemical Bonding)|46 Videos
  • CHEMICAL BONDING AND MOLECULAR STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Multiple Correct(Bond Angle )|5 Videos
  • ATOMIC STRUCTURE

    CENGAGE CHEMISTRY ENGLISH|Exercise Concept Applicationexercise(4.3)|19 Videos
  • CHEMICAL EQUILIBRIUM

    CENGAGE CHEMISTRY ENGLISH|Exercise Subjective type|1 Videos

Similar Questions

Explore conceptually related problems

Which of the following have identical bond order ?

Which of the following have identical bond order ?

Knowledge Check

  • Which of the following facts regarding bond order is not valid ?

    A
    Bond order is given by the number of bonds between the two atoms in a molecule.
    B
    With increase in bond order, bond enthalpy of the molecule decreases.
    C
    Isoelectronic molecules and ions have identical bond orders.
    D
    With increase in bond order, bond length decrease.
  • Similar Questions

    Explore conceptually related problems

    Which of the following have identical bond order?

    Which of the following pairs have identical bond order?

    Which of the following has fractional bond order ?

    Which of the following have fractional bond order and is(are) paramagnetic ?

    Which of the following have highest bond angle ? .

    Which of the following pairs have identical value of bond order?

    Which of the following pairs have identical value of bond order?