Select corrcet orders for corresponding property as indicated in bracket for the following .

Options

A. `NH_(3) gt BiH_(3) gt SbH_(3) gt AsH_(3) gt PH_(3)` (Boiling point)
B. `H_(2)O gtH_(2) Te gt H_(2) Se gt H_S(2)` (Boiling point)
C. `NH_(3) gt PH_(3) gt AsH_(3) gt SbH_(3)` (Basic character)
D. `H_(2)O lt H_(2)S lt H_(2) Se lt H_(2)` Te (Acidic character)

Explanation

To solve the question regarding the correct orders for the properties of nitrogen and oxygen family hydrides, we will analyze each option step by step.

### Step 1: Analyze the Boiling Points of Nitrogen Family Hydrides
1. **Identify the hydrides**: The nitrogen family hydrides are NH3 (ammonia), PH3 (phosphine), AsH3 (arsine), SbH3 (stibine), and BiH3 (bismuthine).
2. **Understand the trend**: As we move down the group from nitrogen to bismuth, the van der Waals forces and molecular weights increase, leading to higher boiling points.
3. **Consider exceptions**: NH3 can form hydrogen bonds, which significantly increases its boiling point compared to other hydrides in the group.
4. **Establish the order**: The correct order based on boiling points is:
- NH3 > BiH3 > SbH3 > AsH3 > PH3

### Step 2: Analyze the Boiling Points of Oxygen Family Hydrides
1. **Identify the hydrides**: The oxygen family hydrides are H2O (water), H2S (hydrogen sulfide), H2Se (hydrogen selenide), and H2Te (hydrogen telluride).
2. **Understand the trend**: Similar to the nitrogen family, as we move down the group, the molecular weight increases, leading to higher boiling points.
3. **Consider hydrogen bonding**: H2O can form strong hydrogen bonds, which raises its boiling point significantly compared to the other hydrides.
4. **Establish the order**: The correct order based on boiling points is:
- H2O > H2Te > H2Se > H2S

### Step 3: Analyze the Basic Character of Nitrogen Family Hydrides
1. **Identify the hydrides**: The basic character of the hydrides is considered for NH3, PH3, AsH3, and SbH3.
2. **Understand the trend**: As we move down the group, the size of the atoms increases, leading to a decrease in charge density and a decrease in the tendency to donate lone pairs.
3. **Establish the order**: The correct order of basicity is:
- NH3 > PH3 > AsH3 > SbH3

### Step 4: Analyze the Acidic Character of Oxygen Family Hydrides
1. **Identify the hydrides**: The acidic character of the hydrides is considered for H2O, H2S, H2Se, and H2Te.
2. **Understand the trend**: As we move down the group, the bond length increases due to the larger atomic size, leading to weaker bonds and easier release of H+ ions.
3. **Establish the order**: The correct order of acidic character is:
- H2Te > H2Se > H2S > H2O

### Summary of Correct Orders
1. **Boiling Points of Nitrogen Family Hydrides**: NH3 > BiH3 > SbH3 > AsH3 > PH3
2. **Boiling Points of Oxygen Family Hydrides**: H2O > H2Te > H2Se > H2S
3. **Basic Character of Nitrogen Family Hydrides**: NH3 > PH3 > AsH3 > SbH3
4. **Acidic Character of Oxygen Family Hydrides**: H2Te > H2Se > H2S > H2O