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Dipole moment of H(2)O(2) is non-zero as...

Dipole moment of `H_(2)O_(2)` is non-zero as

A

Two dipole moments are opposite but unequal

B

Two dipole moments are opposite and equal

C

Two dipole moments are equal but not at `180^(@)`

D

Two dipole moments are equal but non-planar.

Text Solution

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The correct Answer is:
To determine why the dipole moment of hydrogen peroxide (H₂O₂) is non-zero, we can analyze the molecular structure and the arrangement of its bonds step by step. ### Step-by-Step Solution: 1. **Understanding the Molecular Structure of H₂O₂**: - Hydrogen peroxide (H₂O₂) consists of two hydrogen atoms and two oxygen atoms. The molecular structure can be visualized as having an open book-like shape due to the arrangement of the atoms. 2. **Identifying the Bond Polarities**: - Each O-H bond in H₂O₂ is polar because oxygen is more electronegative than hydrogen. This means that the electrons in the O-H bond are drawn closer to the oxygen atom, creating a dipole moment (a vector quantity pointing from the less electronegative atom to the more electronegative atom). 3. **Analyzing the Geometry**: - The two O-H bonds are not in the same plane; they are oriented at an angle to each other. This non-planarity is crucial because it means that the dipole moments of the individual O-H bonds do not cancel each other out. 4. **Resultant Dipole Moment**: - Since the dipole moments of the two O-H bonds are equal in magnitude but are oriented in different directions (due to the non-planar arrangement), they do not cancel each other completely. This results in a net dipole moment for the molecule. 5. **Conclusion**: - Therefore, the dipole moment of H₂O₂ is non-zero because the two dipole moments are equal in magnitude but are non-planar, leading to a resultant dipole moment. ### Final Answer: The dipole moment of H₂O₂ is non-zero because the two dipole moments are equal but non-planar.
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The dipole moment of H_(2)O_(2) is more than that of H_(2)O but H_(2)O_(2) is not a good solvent because :

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Knowledge Check

  • Assertion : The dipole moment in case of BeF_(2) is zero. Reason : The two equal bond dipoles point in opposite directions and cancel the effect of each other.

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    If both assertion and reason are true and reason is the correct explanation of assertion.
    B
    If both assertion and reason are true but reason in not the correct explanation of assertion.
    C
    If assertion is true but reason is false.
    D
    If both assertion and reason are false.
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