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Structure of XeO(2)F(2) is correctly rep...

Structure of `XeO_(2)F_(2)` is correctly represented by

A

B

C

D

Both 2 and 3

Text Solution

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The correct Answer is:
To determine the correct structure of \( \text{XeO}_2\text{F}_2 \), we can follow these steps: ### Step 1: Determine the Valence Electrons - **Xenon (Xe)** has 8 valence electrons (as it is a noble gas). - **Oxygen (O)** has 6 valence electrons, and since there are 2 oxygen atoms, they contribute a total of \( 2 \times 6 = 12 \) electrons. - **Fluorine (F)** has 7 valence electrons, and since there are 2 fluorine atoms, they contribute a total of \( 2 \times 7 = 14 \) electrons. **Total valence electrons = 8 (Xe) + 12 (O) + 14 (F) = 34 electrons.** ### Step 2: Determine Bonding and Lone Pairs - Each oxygen atom will form a double bond with xenon, using 4 electrons (2 electrons per bond). - Each fluorine atom will form a single bond with xenon, using 2 electrons (1 electron per bond). **Total electrons used for bonding:** - 2 double bonds (O) = 4 electrons - 2 single bonds (F) = 2 electrons **Total bonding electrons = 4 + 2 = 6 electrons.** ### Step 3: Calculate Remaining Electrons - Total valence electrons = 34 - Electrons used for bonding = 6 - **Remaining electrons = 34 - 6 = 28 electrons.** ### Step 4: Assign Lone Pairs - The remaining 28 electrons will be assigned as lone pairs. - Since each lone pair consists of 2 electrons, we have \( \frac{28}{2} = 14 \) lone pairs. - However, we need to consider the geometry and the fact that xenon will have a lone pair after forming bonds. ### Step 5: Determine the Geometry - With 4 bond pairs (2 with oxygen and 2 with fluorine) and 1 lone pair, the molecular geometry is based on 5 regions of electron density. - The arrangement of 5 regions of electron density corresponds to a trigonal bipyramidal geometry. - The presence of a lone pair will distort this geometry to a seesaw shape. ### Step 6: Draw the Structure - The structure can be represented as: - Xenon (Xe) at the center. - Two oxygen atoms forming double bonds with xenon. - Two fluorine atoms forming single bonds with xenon. - One lone pair on xenon. ### Conclusion The correct representation of the structure of \( \text{XeO}_2\text{F}_2 \) is a seesaw shape with Xe at the center, two double-bonded oxygens, and two single-bonded fluorines.
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