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STATEMENT-1 : Common oxidation states of...

STATEMENT-1 : Common oxidation states of iron and +2 and +3 in its compound .
and
STATEMENT-2: Iron can have only +2 and +3 oxidation states in its compounds .

A

Statement-1 is True , Statement-2 is True , Statement-2 is a correct explanation for Statement-1

B

Statement-1 is True , Statement-2 is True , Statement-2 is NOT a correct explanation for Statement-1

C

Statement-1 is True , Statement-2 is False

D

Statement-1 is False , Statement-2 is True

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both statements regarding the oxidation states of iron (Fe). ### Step-by-Step Solution: **Step 1: Analyze Statement 1** - **Statement 1**: Common oxidation states of iron are +2 and +3 in its compounds. - Iron (Fe) has an atomic number of 26, which gives it the electronic configuration of [Ar] 3d^6 4s^2. - In its compounds, iron commonly exhibits oxidation states of +2 and +3. - In the +2 oxidation state (Fe^2+), iron loses the two 4s electrons: 3d^6 (4s^0). - In the +3 oxidation state (Fe^3+), iron loses the two 4s electrons and one 3d electron: 3d^5 (4s^0). - **Conclusion**: Statement 1 is true. **Step 2: Analyze Statement 2** - **Statement 2**: Iron can have only +2 and +3 oxidation states in its compounds. - While +2 and +3 are the most common oxidation states of iron, it can exhibit other oxidation states as well. - For example, in potassium ferrate (K2FeO4), iron has an oxidation state of +6. - To determine this, we can set up the equation: - Let the oxidation state of iron be x. - The compound has 4 oxygen atoms (each with a -2 charge), contributing a total of -8. - The two potassium ions (K^+) each contribute +1, totaling +2. - Thus, we have: \[ x + (-8) + 2 = 0 \implies x - 6 = 0 \implies x = +6 \] - **Conclusion**: Statement 2 is false because iron can have oxidation states beyond +2 and +3. **Final Conclusion**: - Statement 1 is true, and Statement 2 is false. Therefore, the correct option is that Statement 1 is true and Statement 2 is false.
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Knowledge Check

  • Oxidation state of iron in Fe(CO)_(4) is

    A
    `+1`
    B
    `-1`
    C
    `+2`
    D
    0
  • The common oxidation state shown by Europium in their compounds is

    A
    `+1`
    B
    `+3`
    C
    `+5`
    D
    `+6`
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