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What is the oxidation state of Mn in pro...

What is the oxidation state of Mn in product formed by the oxidising action of `KMnO_(4)` inneutral medium ?

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To determine the oxidation state of manganese (Mn) in the product formed by the oxidizing action of potassium permanganate (KMnO4) in a neutral medium, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction**: In a neutral medium, potassium permanganate (KMnO4) acts as an oxidizing agent. The product formed from this reaction is manganese dioxide (MnO2). 2. **Write the Balanced Reaction**: The balanced chemical equation for the reaction of KMnO4 in neutral medium can be written as: \[ 2 KMnO_4 + 2 H_2O \rightarrow 2 MnO_2 + 2 KOH + O \] Here, nascent oxygen (O) is also produced. 3. **Determine the Oxidation State of Mn in MnO2**: - In MnO2, we need to find the oxidation state of manganese (Mn). - Let the oxidation state of Mn be \( x \). - The oxidation state of oxygen (O) is -2. - Since there are two oxygen atoms, the total contribution from oxygen is \( 2 \times (-2) = -4 \). - The compound is neutral, so the sum of oxidation states must equal zero: \[ x + (-4) = 0 \] - Solving for \( x \): \[ x - 4 = 0 \implies x = +4 \] 4. **Conclusion**: The oxidation state of manganese (Mn) in the product MnO2 is +4. ### Final Answer: The oxidation state of Mn in the product formed by the oxidizing action of KMnO4 in neutral medium is +4.
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Knowledge Check

  • Why HCl not used to make the mdeium acidic in oxidation reactions of KMnO_(4) in acidic medium ?

    A
    Both HCl and `KMnO_4` act as oxidising agents.
    B
    `KMNO_4` oxidises HCl into `Cl_2` which is also an oxidising agent.
    C
    `KMNO_4` is a weaker oxidising agent than HCl.
    D
    `KMNO_4` acts as a reducing agent in the presence of HCl.
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