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Which of the following compound can b...

Which of the following compound can be resolved into enatiomers ?

A

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given compounds can be resolved into enantiomers, we need to identify whether any of the compounds are chiral. A compound is chiral if it has a chiral center (usually a carbon atom bonded to four different groups) and does not have a plane of symmetry. Let's analyze the compounds step by step: ### Step 1: Identify Chiral Centers 1. **First Compound**: - The first compound has a nitrogen atom with a lone pair of electrons. - Even though nitrogen can be a chiral center, the presence of a lone pair allows for inversion, leading to a racemic mixture. - **Conclusion**: This compound cannot be resolved into enantiomers. 2. **Second Compound**: - The second compound has a carbon atom bonded to four different groups. - Assigning R/S configuration shows that it has a specific stereochemistry. - Taking the mirror image will yield a non-superimposable structure. - **Conclusion**: This compound can be resolved into enantiomers. 3. **Third Compound**: - Analyze the structure for chiral centers. - If it has a carbon bonded to four different groups, it can be chiral. - If it has a plane of symmetry, it cannot be chiral. - **Conclusion**: Check if it has a chiral center. 4. **Fourth Compound**: - Similar to the third compound, check for chiral centers and symmetry. - If it has a chiral center and lacks symmetry, it can be resolved into enantiomers. - **Conclusion**: Check if it has a chiral center. ### Step 2: Final Decision - After analyzing all compounds, we conclude that only the second compound can be resolved into enantiomers due to its chiral center and the absence of symmetry. ### Summary of Findings - **First Compound**: Cannot be resolved into enantiomers (due to inversion). - **Second Compound**: Can be resolved into enantiomers (chiral). - **Third Compound**: Needs further analysis (check for chirality). - **Fourth Compound**: Needs further analysis (check for chirality). ### Final Answer The second compound can be resolved into enantiomers.
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Knowledge Check

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