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Torsion strain is the repulsive interact...

Torsion strain is the repulsive interaction between

A

Electron cloud of two bonds

B

Electron cloud of two `sigma`-bonds

C

Electron cloud of two pie-bonds

D

Electron cloud of two `sigma`-bonds on adjacent atoms

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The correct Answer is:
To solve the question regarding torsion strain, we need to understand what torsion strain is and how it relates to the interactions between electron clouds of bonds in a molecule. ### Step-by-Step Solution: 1. **Understanding Torsion Strain**: Torsion strain, also known as torsional strain, occurs when there is a repulsive interaction between the electron clouds of bonds in a molecule. This strain is particularly significant when the bonds are in a staggered conformation versus an eclipsed conformation. 2. **Identifying the Bonds**: In the context of the question, we need to identify which bonds are involved in torsion strain. The options provided are: - Electron clouds of two bonds - Electron clouds of two sigma bonds - Electron clouds of two pi bonds - Electron clouds of two sigma bonds on adjacent atoms 3. **Analyzing the Options**: - **Electron clouds of two bonds**: This is too vague as it does not specify the type of bonds. - **Electron clouds of two sigma bonds**: This could be a possibility, but it does not specify their position relative to each other. - **Electron clouds of two pi bonds**: Pi bonds generally do not contribute to torsion strain as they are not involved in the same way as sigma bonds. - **Electron clouds of two sigma bonds on adjacent atoms**: This option specifies that the sigma bonds are on adjacent atoms, which is crucial for torsion strain. 4. **Conclusion**: Based on the analysis, the correct answer is **Option D: electron clouds of two sigma bonds on adjacent atoms**. This is because torsion strain arises when the sigma bonds of adjacent atoms are aligned in such a way that their electron clouds repel each other, particularly in an eclipsed conformation. ### Final Answer: Torsion strain is the repulsive interaction between **electron clouds of two sigma bonds on adjacent atoms**.
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