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CH(3)-CH=CH-CHO overset(A)to CH(3)-CH=CH...

`CH_(3)-CH=CH-CHO overset(A)to CH_(3)-CH=CH-CH_(3)`
The best suitable reagent A is

A

`C_(3)H_(8)S_(2)//H_(2)//Ni`

B

`N_(2)H_(4)//KOH`

C

`Zn-Hg//conc.HCl`

D

HI/P(red)

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the conversion of the compound \( CH_3-CH=CH-CHO \) to \( CH_3-CH=CH-CH_3 \), we need to identify the best suitable reagent \( A \) that facilitates this transformation. The aldehyde group (CHO) needs to be removed and replaced with a hydrogen atom, effectively converting the aldehyde into an alkene. ### Step-by-Step Solution: 1. **Identify the Functional Groups**: - The starting compound \( CH_3-CH=CH-CHO \) contains an aldehyde group (CHO) at the end of the carbon chain. - The target compound \( CH_3-CH=CH-CH_3 \) is an alkene with no functional groups. 2. **Understand the Reaction Type**: - The transformation involves the reduction of the aldehyde group to a methylene group (–CH2–), which is characteristic of a reduction reaction. 3. **Select the Appropriate Reagent**: - The reagent that can effectively convert an aldehyde to a corresponding alkane is the Wolff-Kishner reduction reagent, which involves hydrazine (\( N_2H_4 \)) followed by a strong base like potassium hydroxide (KOH) in the presence of ethylene glycol. 4. **Write the Reaction Mechanism**: - The hydrazine reacts with the aldehyde to form a hydrazone intermediate. - Upon heating with KOH and ethylene glycol, nitrogen gas (\( N_2 \)) is eliminated, resulting in the formation of the alkene. 5. **Conclusion**: - The best suitable reagent \( A \) for this transformation is \( N_2H_4 \) (hydrazine) followed by KOH in ethylene glycol. ### Final Answer: The best suitable reagent \( A \) is \( N_2H_4 \) (hydrazine) followed by KOH in ethylene glycol.
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