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The shape of BrF3 molecule is slightly b...

The shape of `BrF_3` molecule is slightly bent 'T' , because

A

The lone pairs occupy the equatorial position to minimize lone pair- lone pair and the bond pair-lone pair repulsions

B

The axial fluroine atoms will be bent towards the equatorial fluorine in orer to minimize the lone pair-lonepair repulsions.

C

According to the VSEPR theory, one lone pair of Br occupies the equatorial position and the second one occupied the axial position in order to minimize the lone pair-lone pair repulsion

D

Both (1) and (2)

Text Solution

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The correct Answer is:
To determine why the shape of the BrF3 molecule is slightly bent 'T', we can follow these steps: ### Step 1: Identify the Central Atom and Valence Electrons - The central atom in BrF3 is Bromine (Br). - Bromine is a halogen and has 7 valence electrons. ### Step 2: Determine Bonding and Lone Pairs - In BrF3, Bromine forms bonds with 3 Fluorine (F) atoms. - Each bond uses one valence electron from Bromine, so 3 electrons are used for bonding. - This leaves 4 valence electrons remaining for Bromine, which means there are 2 lone pairs (since each lone pair consists of 2 electrons). ### Step 3: Calculate the Steric Number - The steric number is calculated as the number of bond pairs plus the number of lone pairs. - In BrF3, there are 3 bond pairs and 2 lone pairs, so the steric number is 5 (3 + 2 = 5). ### Step 4: Determine Hybridization and Geometry - For a steric number of 5, the hybridization is sp³d. - The geometry corresponding to sp³d hybridization is trigonal bipyramidal. ### Step 5: Analyze the Arrangement of Lone Pairs and Bond Pairs - In a trigonal bipyramidal arrangement, there are two positions: axial and equatorial. - To minimize repulsions, the two lone pairs will occupy the equatorial positions, as lone pair-lone pair repulsion is greater than bond pair-bond pair repulsion. ### Step 6: Determine the Final Shape - With two lone pairs in the equatorial positions, the three bond pairs (the fluorine atoms) will be arranged around the Bromine atom. - The axial fluorine atoms will slightly bend towards the equatorial fluorine atom to further minimize repulsions. - This results in a slightly bent 'T' shape for the BrF3 molecule. ### Conclusion - The shape of the BrF3 molecule is slightly bent 'T' due to the arrangement of lone pairs and bond pairs in such a way as to minimize repulsions according to VSEPR theory.
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