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The magnetic moment of .25Mn in ionic st...

The magnetic moment of `._25Mn` in ionic state is `sqrt(15)B.M`, then Mn is in:

A

1

B

2

C

3

D

4

Text Solution

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The correct Answer is:
To determine the oxidation state of manganese (Mn) in the ionic state given that its magnetic moment is \(\sqrt{15} \, \text{B.M.}\), we can follow these steps: ### Step 1: Use the Magnetic Moment Formula The formula for calculating the magnetic moment (\(\mu\)) of an ion is given by: \[ \mu = \sqrt{n(n + 2)} \, \text{B.M.} \] where \(n\) is the number of unpaired electrons. ### Step 2: Set Up the Equation We know from the question that: \[ \mu = \sqrt{15} \, \text{B.M.} \] Thus, we can set up the equation: \[ \sqrt{n(n + 2)} = \sqrt{15} \] ### Step 3: Square Both Sides Squaring both sides of the equation to eliminate the square root gives: \[ n(n + 2) = 15 \] ### Step 4: Rearrange the Equation Rearranging the equation, we get: \[ n^2 + 2n - 15 = 0 \] ### Step 5: Factor the Quadratic Equation Now, we can factor the quadratic: \[ (n + 5)(n - 3) = 0 \] This gives us two possible solutions for \(n\): \[ n = -5 \quad \text{or} \quad n = 3 \] Since \(n\) must be a non-negative integer, we take: \[ n = 3 \] ### Step 6: Determine the Oxidation State The value of \(n\) represents the number of unpaired electrons. Manganese (Mn) has an atomic number of 25, and its ground state electronic configuration is: \[ [Ar] \, 4s^2 \, 3d^5 \] In the ionic state, Mn loses electrons. In this case, since there are 3 unpaired electrons, it means that 2 electrons from the \(4s\) subshell are lost, and 1 electron from the \(3d\) subshell is also lost. Thus, the oxidation state of manganese can be calculated as follows: - The original number of electrons in Mn is 25. - After losing 4 electrons (2 from \(4s\) and 2 from \(3d\)), the oxidation state is: \[ \text{Oxidation state} = 25 - 4 = +4 \] ### Final Answer Therefore, the oxidation state of manganese in this ionic state is \(+4\). ---

To determine the oxidation state of manganese (Mn) in the ionic state given that its magnetic moment is \(\sqrt{15} \, \text{B.M.}\), we can follow these steps: ### Step 1: Use the Magnetic Moment Formula The formula for calculating the magnetic moment (\(\mu\)) of an ion is given by: \[ \mu = \sqrt{n(n + 2)} \, \text{B.M.} \] where \(n\) is the number of unpaired electrons. ...
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