Home
Class 12
CHEMISTRY
Statement-1 : In caro's acid the oxidati...

Statement-1 : In caro's acid the oxidation state of sulphur is `+5`
Statement-2: In caro's acid, there is one peroxolinkage. `(-O-O-)`

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-15

B

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-16

C

Statement-1 is True, Statement-2 is False.

D

Statement-1 is False, Statement-2 is True.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question regarding Caro's acid (H2SO5) and the oxidation state of sulfur, we will follow these steps: ### Step 1: Identify the structure of Caro's acid Caro's acid is represented by the chemical formula H2SO5. It consists of one sulfur atom and five oxygen atoms. The structure can be drawn as follows: - Sulfur (S) is bonded to four oxygen atoms: two of these are double-bonded (O=) and one is single-bonded (O) to a hydroxyl group (OH). The fourth oxygen is part of a peroxy linkage (-O-O-). ### Step 2: Assign oxidation states To determine the oxidation state of sulfur (S) in Caro's acid, we will assign oxidation states to each atom: - The oxidation state of hydrogen (H) is +1. - The oxidation state of oxygen (O) in a peroxy linkage (-O-O-) is -1. - The oxidation state of the remaining oxygen atoms (not in peroxy linkage) is -2. ### Step 3: Set up the equation Since Caro's acid is a neutral molecule, the sum of the oxidation states must equal zero. We can set up the equation as follows: - For two hydrogen atoms: 2 × (+1) = +2 - For one sulfur atom: 1 × (oxidation state of S) = X - For two oxygen atoms in the peroxy linkage: 2 × (-1) = -2 - For the remaining three oxygen atoms: 3 × (-2) = -6 The equation becomes: \[ +2 + X - 2 - 6 = 0 \] ### Step 4: Solve for the oxidation state of sulfur Now, we simplify the equation: \[ +2 + X - 2 - 6 = 0 \] \[ X - 6 = 0 \] \[ X = +6 \] ### Step 5: Analyze the statements - **Statement 1**: "In Caro's acid, the oxidation state of sulfur is +5." This statement is **false** because we calculated the oxidation state of sulfur to be +6. - **Statement 2**: "In Caro's acid, there is one peroxy linkage (-O-O-)." This statement is **true** as we identified the presence of a peroxy linkage in the structure. ### Conclusion Based on the analysis: - Statement 1 is false. - Statement 2 is true. Thus, the correct answer is that Statement 1 is false and Statement 2 is true. ### Final Answer The correct option is D: Statement 1 is false, Statement 2 is true.

To solve the given question regarding Caro's acid (H2SO5) and the oxidation state of sulfur, we will follow these steps: ### Step 1: Identify the structure of Caro's acid Caro's acid is represented by the chemical formula H2SO5. It consists of one sulfur atom and five oxygen atoms. The structure can be drawn as follows: - Sulfur (S) is bonded to four oxygen atoms: two of these are double-bonded (O=) and one is single-bonded (O) to a hydroxyl group (OH). The fourth oxygen is part of a peroxy linkage (-O-O-). ### Step 2: Assign oxidation states To determine the oxidation state of sulfur (S) in Caro's acid, we will assign oxidation states to each atom: ...
Promotional Banner

Topper's Solved these Questions

  • P BLOCK ELEMENTS

    RESONANCE ENGLISH|Exercise Exercise 2 part 1 SUBJECTIVE|16 Videos
  • P BLOCK ELEMENTS

    RESONANCE ENGLISH|Exercise Exercise 2 part 2 OBJECTIVE|52 Videos
  • P BLOCK ELEMENTS

    RESONANCE ENGLISH|Exercise Exercise 1 part 2 objective que|48 Videos
  • NUCLEAR CHEMISTRY

    RESONANCE ENGLISH|Exercise STAGE-II|1 Videos
  • P-BLOCK ELEMENT (BORON AND CARBON FAMILY)

    RESONANCE ENGLISH|Exercise PART - III : OLYMPIAD PROBLEMS (PREVIOUS YEARS) STAGE - V (INTERNATIONAL CHEMISTRY OLYMPIAD (IChO)) Problem 3|8 Videos

Similar Questions

Explore conceptually related problems

What is oxidation state of sulphur is Caro's acid ?

Oxidation state of O in KO_(2) is

What is the hybrid state and oxidation state of sulphur in Caro's acid ?

In the compound Na_(2)S_(2)O_(3) , the oxidation state of sulphur is:

The average oxidation state of sulphur atom in S_4O_6^(2-) ion is

The oxidation number of sulphur in caro's acid is +x. What is value of x.

The oxidation state of S-atoms in Caro's and Marshall's acids are :

The oxidation state of S-atoms in Caro's and Marshall's acids are:

The oxidation state of sulphur in sodium tetrathionate ( Na_(2)S_(4)O_(6) ) is :

The oxidation number of sulphur in H_(2)S_(2)O_(8) is:

RESONANCE ENGLISH-P BLOCK ELEMENTS-Exercise 1 part 3 ASSERTION/REASONING
  1. How many grams of dibasic acid (mol. weight 200) should be present in ...

    Text Solution

    |

  2. How many grams of dibasic acid (mol. weight 200) should be present in ...

    Text Solution

    |

  3. Statement-1 : Liquid NH(3) is used for refrigeration. Statement-2 : ...

    Text Solution

    |

  4. How many grams of dibasic acid (mol. weight 100) should be present in ...

    Text Solution

    |

  5. How many grams of dibasic acid (mol. weight 100) should be present in ...

    Text Solution

    |

  6. Calculate the number of moles in 127 grams of CaOCl2

    Text Solution

    |

  7. Statement-1 : NaH(2)PO(2) is an acid salt. Statement-2 : It contains...

    Text Solution

    |

  8. Calculate the number of moles in 254 grams of CaOCl2

    Text Solution

    |

  9. Calculate the number of moles in 369 grams of CaOCl2 ​

    Text Solution

    |

  10. Statement-1 : Electrovalency of oxygen is two (O^(2-)) Statement-2 :...

    Text Solution

    |

  11. Statement-1 : At room temperature oxygen exists as a diatomic gas, whe...

    Text Solution

    |

  12. Statement-1 : Anhydrous BaO(2) is not used for preparing H(2)O(2). S...

    Text Solution

    |

  13. Statement-1 : Mobility of mercury (Hg) decreases and its starts sticki...

    Text Solution

    |

  14. Statement-1 : Sulphuric acid is less viscous than water due to intermo...

    Text Solution

    |

  15. Statement-1 : In caro's acid the oxidation state of sulphur is +5 St...

    Text Solution

    |

  16. Draw the Structure of : Thiosulphuric acid

    Text Solution

    |

  17. Assertion (A): Pink coloured solution of potassium permanganate turns ...

    Text Solution

    |

  18. Statement-1 : H(2)O(2) is stored in wax-lined glass. Statement-2 : P...

    Text Solution

    |

  19. Calculate the number of moles in 316 grams of KMnO4

    Text Solution

    |