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Silicon is the second most abundant elem...

Silicon is the second most abundant element `(~27.2%)` in the earth's after oxygen `(45.5 %)` Carbon. Silicon, germanium, tin and lead constitute the group `14` of the periodic table. Chemistry of silicon is distinctly different from that of carbon.
For example, under standard conditions `CO_(2)` is a gas whereas `SiO_(2)` is a covalent solid.
Draw the structures of `CO_(2)` and `SiO_(2)`

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To draw the structures of carbon dioxide (CO₂) and silicon dioxide (SiO₂), we will follow these steps: ### Step 1: Draw the Lewis Structure for Carbon Dioxide (CO₂) 1. **Identify the central atom**: Carbon (C) is the central atom because it is less electronegative than oxygen (O). 2. **Count the valence electrons**: Carbon has 4 valence electrons, and each oxygen has 6 valence electrons. Therefore, the total number of valence electrons is: \[ 4 \text{ (from C)} + 2 \times 6 \text{ (from O)} = 16 \text{ valence electrons} \] 3. **Arrange the atoms**: Place carbon in the center and the two oxygen atoms on either side. 4. **Form bonds**: Connect the carbon atom to each oxygen atom with a double bond to satisfy the octet rule for all atoms. Each double bond consists of 4 electrons (2 pairs). 5. **Distribute remaining electrons**: After forming double bonds, each oxygen will have 4 electrons remaining as lone pairs. The Lewis structure of CO₂ can be represented as: ``` O=C=O ``` Where each "=" represents a double bond. ### Step 2: Draw the Lewis Structure for Silicon Dioxide (SiO₂) 1. **Identify the central atom**: Silicon (Si) is the central atom, similar to carbon in CO₂. 2. **Count the valence electrons**: Silicon has 4 valence electrons, and each oxygen has 6 valence electrons. Therefore, the total number of valence electrons is: \[ 4 \text{ (from Si)} + 2 \times 6 \text{ (from O)} = 16 \text{ valence electrons} \] 3. **Arrange the atoms**: Place silicon in the center and the two oxygen atoms on either side. 4. **Form bonds**: Connect the silicon atom to each oxygen atom with a double bond. 5. **Distribute remaining electrons**: After forming double bonds, each oxygen will have 4 electrons remaining as lone pairs. The Lewis structure of SiO₂ can be represented as: ``` O=Si=O ``` Where each "=" represents a double bond. ### Final Structures - **Carbon Dioxide (CO₂)**: ``` O=C=O ``` - **Silicon Dioxide (SiO₂)**: ``` O=Si=O ```
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Silicon is the second most abundant element (~27.2%) in the earth's after oxygen (45.5 %) Carbon. Silicon, germanium, tin and lead constitute the group 14 of the periodic table. Chemistry of silicon is distinctly different from that of carbon. For example, under standard conditions CO_(2) is a gas whereas SiO_(2) is a covalent solid. Draw the structure of a cyclic silicate having structural formula of [Si_(6)O_(18)]^(n-) .Also determine the value of n [Hint : SiO_(4)^(4-) can be shown as unit]

Silicon is the second most abundant element (~27.2%) in the earth's after oxygen (45.5 %) Carbon. Silicon, germanium, tin and lead constitute the group 14 of the periodic table. Chemistry of silicon is distinctly different from that of carbon. For example, under standard conditions CO_(2) is a gas whereas SiO_(2) is a covalent solid. Draw the structure of the anion present in pyroxene (MgCaSi_(2)O_(6)) . Silicones are important synthetic polymers which find extensive applications due to their chemical inertness and water repelling nature. Thet are produced via the following reactions. 2 C_(6)H_(5)Cl +Si underset("370 K")overset("Cu")to A A underset(-HCl)overset(H_(2)O)to B

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