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Which of the following perfome reaction ...

Which of the following perfome reaction with `I_(2)//OH^(-)` ?

A

`CH_(3)COCH_(2)CH_(3)`

B

`CH_(3)CONH_(2)`

C

`C_(6)H_(5)COCH_(3)`

D

`CH_(3)CHO`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compounds react with \( I_2 \) and \( OH^- \), we need to identify the structural requirements for such reactions. The key requirement is that the compound must have a methyl group adjacent to a carbonyl group (i.e., a methyl ketone or a suitable aldehyde). This is because the reaction leads to the formation of iodoform. ### Step-by-Step Solution: 1. **Identify the Compounds**: We need to analyze each of the given compounds to see if they have a methyl group adjacent to a carbonyl group. 2. **Examine Compound A**: - The structure is \( CH_3COCH_2CH_3 \) (a methyl ketone). - It has a methyl group (\( CH_3 \)) adjacent to the carbonyl (\( CO \)). - **Conclusion**: This compound will react with \( I_2 \) and \( OH^- \) and give the iodoform test. 3. **Examine Compound B**: - The structure is an amide. - Amides do not have the required methyl group adjacent to a carbonyl for this reaction. - **Conclusion**: This compound will NOT react with \( I_2 \) and \( OH^- \). 4. **Examine Compound C**: - The structure has a methyl group adjacent to a carbonyl. - This compound can also undergo the iodoform reaction. - **Conclusion**: This compound will react with \( I_2 \) and \( OH^- \). 5. **Examine Compound D**: - The structure is \( CH_3C(OH) \) (an alcohol with a methyl group). - It has a methyl group adjacent to a carbonyl (considering the keto form). - **Conclusion**: This compound will also react with \( I_2 \) and \( OH^- \). 6. **Final Answer**: The compounds that will react with \( I_2 \) and \( OH^- \) are A, C, and D.

To determine which compounds react with \( I_2 \) and \( OH^- \), we need to identify the structural requirements for such reactions. The key requirement is that the compound must have a methyl group adjacent to a carbonyl group (i.e., a methyl ketone or a suitable aldehyde). This is because the reaction leads to the formation of iodoform. ### Step-by-Step Solution: 1. **Identify the Compounds**: We need to analyze each of the given compounds to see if they have a methyl group adjacent to a carbonyl group. 2. **Examine Compound A**: - The structure is \( CH_3COCH_2CH_3 \) (a methyl ketone). ...
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