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An alkene (A)C(16)H(16) on ozonolysis gi...

An alkene `(A)C_(16)H_(16)` on ozonolysis gives only one product `(B)(C_(8)H_(8)O)`. Compound (B) on reaction with `NH_(2)OH` followed by reaction with `H_(2)SO_(4), Delta` gives N - methyl benzamide the compound 'A' is -

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An organic compound (A), C_(8)H_(4) O_(3) in dry benzene in the presene of anhydorus AlCl_(3) gives compound (B) . Compound (B) on treatment with PCl_(5) followed by reaction with H_(2)//Pd (BaSO_(4)) gives compound (C) which on reaction with hydrazine gives a cyclised compound (D),(C_(14) H_(10) N_(2)) Idenyify (A),(B),(C) and (D) . Explain the formation of (D) from (C) .

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Knowledge Check

  • Compound (A) C_8H_6O_2 on treatment with aq. NaOH followed by acidification gives (B) C_3H_2O_3 which on oxidation gives benzoic acid only:

    A
    B
    C
    D

  • A compound (A) C_(5)H_(10) Cl_(2) on hydrolysis gives C_(5)H_(10)O which reacts with NH_(2)OH , forms iodoform but does not give Fehling test (A) is :

    A
    `H_(3)C-overset(CI)overset(|)underset(CI)underset(|)C-CH_(2)CH_(2)CH_(3)`
    B
    `CH_(3)CH_(2)- overset(CI) overset(|) underset(CI)underset(|)C- CH_(2)CH_(3) `
    C
    `overset(CI)overset(|) underset(CI)underset(|) CHCH_(2) CH_(2)CH_(2)CH_(3)`
    D
    `CH_(3)CH_(2) overset(CI)overset(|)CH- overset(CI)overset(|)CHCH_(3)`

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