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The correct statements among (a) to (d) ...

The correct statements among (a) to (d) are
(a). Saline hyddrides produces `H_(2)` gas when reaction with `H_(2)O`.
(b). Reaction of `LiAlH_(4)` with `BF_(3)` leads to `B_(2)H_(6)`
(c). `PH_(3)` and `CH_(4)` are electron rich and electron precise hydrides, respectively.
(d). `HF` and `CH_(4)` are called as molecular hydrides.

A

c and d only

B

a, c and d only

C

a, b, and c only

D

a, b, c and d only

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct statements among (a) to (d), let's analyze each option step by step. ### Step 1: Analyze Option (a) **Statement:** Saline hydrides produce `H2` gas when reacting with `H2O`. **Explanation:** Saline hydrides are ionic hydrides formed with alkali and alkaline earth metals. When saline hydrides react with water, they produce a metal hydroxide and hydrogen gas. For example, sodium hydride (NaH) reacts with water to produce sodium hydroxide (NaOH) and hydrogen gas (H2). - **Reaction:** NaH + H2O → NaOH + H2 **Conclusion:** This statement is **correct**. ### Step 2: Analyze Option (b) **Statement:** Reaction of `LiAlH4` with `BF3` leads to `B2H6`. **Explanation:** Lithium aluminum hydride (LiAlH4) reacts with boron trifluoride (BF3) to form diborane (B2H6). The reaction can be summarized as: - **Reaction:** 2 LiAlH4 + 3 BF3 → B2H6 + 3 LiF + AlF3 **Conclusion:** This statement is **correct**. ### Step 3: Analyze Option (c) **Statement:** `PH3` and `CH4` are electron-rich and electron-precise hydrides, respectively. **Explanation:** - **PH3 (Phosphine):** Phosphorus has a lone pair, making PH3 an electron-rich hydride. - **CH4 (Methane):** Carbon in methane has four bonds and no lone pairs, making it an electron-precise hydride. **Conclusion:** This statement is **correct**. ### Step 4: Analyze Option (d) **Statement:** `HF` and `CH4` are called molecular hydrides. **Explanation:** Both HF (hydrogen fluoride) and CH4 (methane) are molecular compounds where hydrogen is covalently bonded to other elements (fluorine and carbon, respectively). They can be classified as molecular hydrides. **Conclusion:** This statement is **correct**. ### Final Conclusion All options (a), (b), (c), and (d) are correct. ### Summary of Correct Statements: - (a) Correct - (b) Correct - (c) Correct - (d) Correct

To determine the correct statements among (a) to (d), let's analyze each option step by step. ### Step 1: Analyze Option (a) **Statement:** Saline hydrides produce `H2` gas when reacting with `H2O`. **Explanation:** Saline hydrides are ionic hydrides formed with alkali and alkaline earth metals. When saline hydrides react with water, they produce a metal hydroxide and hydrogen gas. For example, sodium hydride (NaH) reacts with water to produce sodium hydroxide (NaOH) and hydrogen gas (H2). - **Reaction:** NaH + H2O → NaOH + H2 ...
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Knowledge Check

  • The reaction of C_(6)H_(5)CH=CHCHO with LiAlH_(4) gives :

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    B
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    B
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