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Energy of electron is given by E=-2.178x...

Energy of electron is given by `E=-2.178xx10^(-18)((Z^(2))/(n^(2)))`J.
Wavelength of light required to excited an electron in an hydrogen atom from level n=1 to n=2 will be `(h=6.62xx10^(-34)J*s and c=3.0xx10^(8)m*s^(-1))`-

A

`1.214xx10^(-7)m`

B

`2.816xx10^(-7)m`

C

`6.500xx10^(-7)m`

D

`8.500xx10^(-7)m`

Text Solution

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The correct Answer is:
To solve the problem of finding the wavelength of light required to excite an electron in a hydrogen atom from level \( n=1 \) to \( n=2 \), we will follow these steps: ### Step 1: Identify the Energy Levels The energy of an electron in a hydrogen atom is given by the formula: \[ E = -2.178 \times 10^{-18} \frac{Z^2}{n^2} \text{ J} \] For hydrogen, \( Z = 1 \). Therefore, the energy levels for \( n=1 \) and \( n=2 \) are: - For \( n=1 \): \[ E_1 = -2.178 \times 10^{-18} \frac{1^2}{1^2} = -2.178 \times 10^{-18} \text{ J} \] - For \( n=2 \): \[ E_2 = -2.178 \times 10^{-18} \frac{1^2}{2^2} = -2.178 \times 10^{-18} \times \frac{1}{4} = -5.445 \times 10^{-19} \text{ J} \] ### Step 2: Calculate the Energy Difference The energy required to excite the electron from \( n=1 \) to \( n=2 \) is given by: \[ \Delta E = E_2 - E_1 \] Substituting the values we calculated: \[ \Delta E = -5.445 \times 10^{-19} - (-2.178 \times 10^{-18}) = -5.445 \times 10^{-19} + 2.178 \times 10^{-18} \] \[ \Delta E = 1.6335 \times 10^{-18} \text{ J} \] ### Step 3: Relate Energy to Wavelength The energy of a photon is also given by the equation: \[ E = \frac{hc}{\lambda} \] Where: - \( h = 6.626 \times 10^{-34} \text{ J s} \) - \( c = 3.0 \times 10^8 \text{ m/s} \) Setting the two expressions for energy equal gives: \[ \frac{hc}{\lambda} = \Delta E \] Rearranging for \( \lambda \): \[ \lambda = \frac{hc}{\Delta E} \] ### Step 4: Substitute the Values Substituting the known values: \[ \lambda = \frac{(6.626 \times 10^{-34} \text{ J s})(3.0 \times 10^8 \text{ m/s})}{1.6335 \times 10^{-18} \text{ J}} \] Calculating the numerator: \[ hc = 6.626 \times 10^{-34} \times 3.0 \times 10^8 = 1.9878 \times 10^{-25} \text{ J m} \] Now substituting this into the equation for \( \lambda \): \[ \lambda = \frac{1.9878 \times 10^{-25}}{1.6335 \times 10^{-18}} \approx 1.216 \times 10^{-7} \text{ m} \] ### Step 5: Convert to Appropriate Units To express this in nanometers (1 nm = \( 10^{-9} \) m): \[ \lambda \approx 121.6 \text{ nm} \] ### Final Answer The wavelength of light required to excite an electron in a hydrogen atom from level \( n=1 \) to \( n=2 \) is approximately \( 121.6 \text{ nm} \). ---

To solve the problem of finding the wavelength of light required to excite an electron in a hydrogen atom from level \( n=1 \) to \( n=2 \), we will follow these steps: ### Step 1: Identify the Energy Levels The energy of an electron in a hydrogen atom is given by the formula: \[ E = -2.178 \times 10^{-18} \frac{Z^2}{n^2} \text{ J} \] For hydrogen, \( Z = 1 \). Therefore, the energy levels for \( n=1 \) and \( n=2 \) are: ...
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Explore conceptually related problems

Energy of an electron is givem by E = - 2.178 xx 10^-18 J ((Z^2)/(n^2)) . Wavelength of light required to excited an electron in an hydrogen atom from level n = 1 to n = 2 will be (h = 6.62 xx 10^-34 Js and c = 3.0 xx 10^8 ms^-1 ).

Energy of an electron in an excited hydrogen atom is -3.4eV . Its angualr momentum will be: h = 6.626 xx 10^(-34) J-s .

Knowledge Check

  • The ionisation enthalpy of hydrogen atom is 1.312 xx 10^6" J mol"^(-1) . The energy required to excite the electron in the atom from n = 1 to n = 2 is

    A
    `8.51xx10^(5)"J mol"^(-1)`
    B
    `6.56 xx10^(5)"J mol"^(-1)`
    C
    `7.56 xx10^(5)"J mol"^(-1)`
    D
    `9.84 xx10^(5)"J mol"^(-1)`
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