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In Be(2) the bond order is...

In `Be_(2)` the bond order is

A

one

B

zero

C

two

D

one-half

Text Solution

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The correct Answer is:
To determine the bond order of the molecule \( \text{Be}_2 \), we can follow these steps: ### Step 1: Determine the total number of electrons Beryllium (Be) has an atomic number of 4, which means each beryllium atom has 4 electrons. Since there are 2 beryllium atoms in \( \text{Be}_2 \), the total number of electrons is: \[ \text{Total electrons} = 2 \times 4 = 8 \] ### Step 2: Write the molecular orbital configuration The molecular orbital (MO) configuration for \( \text{Be}_2 \) can be filled based on the energy levels of the molecular orbitals. The order of filling for the first 8 electrons is as follows: - \( \sigma_{1s}^2 \) - \( \sigma^*_{1s}^2 \) - \( \sigma_{2s}^2 \) - \( \sigma^*_{2s}^2 \) Thus, the complete molecular orbital configuration for \( \text{Be}_2 \) is: \[ \sigma_{1s}^2 \sigma^*_{1s}^2 \sigma_{2s}^2 \sigma^*_{2s}^2 \] ### Step 3: Count the number of electrons in bonding and anti-bonding orbitals - **Bonding molecular orbitals (BMO)**: - \( \sigma_{1s} \): 2 electrons - \( \sigma_{2s} \): 2 electrons - Total in bonding MOs, \( n_B = 2 + 2 = 4 \) - **Anti-bonding molecular orbitals (ABMO)**: - \( \sigma^*_{1s} \): 2 electrons - \( \sigma^*_{2s} \): 2 electrons - Total in anti-bonding MOs, \( n_A = 2 + 2 = 4 \) ### Step 4: Calculate the bond order The bond order can be calculated using the formula: \[ \text{Bond Order} = \frac{1}{2} (n_B - n_A) \] Substituting the values we found: \[ \text{Bond Order} = \frac{1}{2} (4 - 4) = \frac{1}{2} \times 0 = 0 \] ### Conclusion The bond order of \( \text{Be}_2 \) is 0, indicating that there is no net bond between the two beryllium atoms.

To determine the bond order of the molecule \( \text{Be}_2 \), we can follow these steps: ### Step 1: Determine the total number of electrons Beryllium (Be) has an atomic number of 4, which means each beryllium atom has 4 electrons. Since there are 2 beryllium atoms in \( \text{Be}_2 \), the total number of electrons is: \[ \text{Total electrons} = 2 \times 4 = 8 \] ...
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  • Assertion : F_(2)and O_(2)^(2-) have bond order 1 while N_(2),CO and NO^(+) have bond order 3. Reason : Higher the bond order, higher is the stability of the molecule.

    A
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    B
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    C
    If assertion is true but reason is false.
    D
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