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A simplified applified of MO theory to t...

A simplified applified of `MO` theory to the hypotheritical molecule `OF` would gives its bond order as:

A

2

B

1.5

C

`1.0`

D

0.5

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To determine the bond order of the hypothetical molecule OF (oxygen difluoride) using molecular orbital (MO) theory, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Atomic Numbers and Electron Configuration**: - Oxygen (O) has an atomic number of 8, which means it has 8 electrons. - Fluorine (F) has an atomic number of 9, which means it has 9 electrons. 2. **Calculate the Total Number of Electrons in OF**: - Total electrons = Electrons from Oxygen + Electrons from Fluorine - Total electrons = 8 (from O) + 9 (from F) = 17 electrons. 3. **Construct the Molecular Orbital Diagram**: - The molecular orbitals for O and F can be filled based on their respective electron configurations. - For O: - 1s: 2 electrons (σ1s²) - 2s: 2 electrons (σ2s²) - 2p: 4 electrons (σ2p², π2p²) - For F: - 1s: 2 electrons (σ1s²) - 2s: 2 electrons (σ2s²) - 2p: 5 electrons (σ2p², π2p³) 4. **Fill the Molecular Orbitals**: - The order of filling the molecular orbitals is: - σ1s, σ*1s, σ2s, σ*2s, σ2p, π2p, π*2p - Fill the orbitals with the total of 17 electrons: - σ1s: 2 - σ*1s: 2 - σ2s: 2 - σ*2s: 2 - σ2p: 2 - π2p: 5 - π*2p: 2 (remaining electrons) 5. **Count the Electrons in Bonding and Antibonding Orbitals**: - Bonding orbitals: - σ1s (2) + σ2s (2) + σ2p (2) + π2p (5) = 11 electrons - Antibonding orbitals: - σ*1s (2) + σ*2s (2) + π*2p (2) = 6 electrons 6. **Calculate the Bond Order**: - Bond order is calculated using the formula: \[ \text{Bond Order} = \frac{1}{2} \times (\text{Number of electrons in bonding orbitals} - \text{Number of electrons in antibonding orbitals}) \] - Substituting the values: \[ \text{Bond Order} = \frac{1}{2} \times (11 - 6) = \frac{1}{2} \times 5 = 2.5 \] 7. **Conclusion**: - The bond order of the molecule OF is 2.5.

To determine the bond order of the hypothetical molecule OF (oxygen difluoride) using molecular orbital (MO) theory, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Atomic Numbers and Electron Configuration**: - Oxygen (O) has an atomic number of 8, which means it has 8 electrons. - Fluorine (F) has an atomic number of 9, which means it has 9 electrons. ...
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Knowledge Check

  • The bond order of a molecule is given by

    A
    the difference between the number of electrons in bonding and antibonding orbitals.
    B
    total number of electrons in bonding and antibonding orbitals.
    C
    Twice the difference between the number of electrons in bonding and antibonding orbitals.
    D
    Half the difference between umbe of electrons in bonding and antibonding orbitals.
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