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For the reaction, C+O(2) rarr CO(2),D...

For the reaction,
`C+O_(2) rarr CO_(2),DeltaH=-393 J`
`2Zn + O_(2) rarr 2ZnO, DeltaH=-412 J`

A

Carbon can reduce ZnO to Zn

B

Oxidation of carbon is not feasible

C

Oxidation of Zn is not feasible

D

Zn liberates more heat than carbon during oxidation

Text Solution

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The correct Answer is:
To solve the question regarding the reactions of carbon and zinc with oxygen, we will analyze the given reactions and their enthalpy changes step by step. ### Given Reactions: 1. **Carbon Reaction:** \[ C + O_2 \rightarrow CO_2, \quad \Delta H = -393 \, \text{J} \] 2. **Zinc Reaction:** \[ 2Zn + O_2 \rightarrow 2ZnO, \quad \Delta H = -412 \, \text{J} \] ### Step 1: Understanding the Reactions - The first reaction shows that carbon reacts with oxygen to produce carbon dioxide, releasing 393 J of energy. - The second reaction shows that zinc reacts with oxygen to produce zinc oxide, releasing 412 J of energy. ### Step 2: Analyzing Reduction and Oxidation - We need to determine if carbon can reduce zinc oxide (ZnO) to zinc (Zn). This involves reversing the reaction of zinc oxide formation. ### Step 3: Reverse the Zinc Reaction - The reverse of the zinc oxide formation can be written as: \[ 2ZnO \rightarrow 2Zn + O_2 \] - The enthalpy change for the reverse reaction will be the positive value of the original reaction: \[ \Delta H = +412 \, \text{J} \] ### Step 4: Combine the Reactions - Now, we can combine the reactions: 1. Carbon reacts with oxygen to form carbon dioxide: \[ C + O_2 \rightarrow CO_2 \quad (\Delta H = -393 \, \text{J}) \] 2. Zinc oxide decomposes to zinc and oxygen: \[ 2ZnO \rightarrow 2Zn + O_2 \quad (\Delta H = +412 \, \text{J}) \] - When we add these two reactions, the oxygen from the first reaction will cancel with the oxygen from the second reaction: \[ C + 2ZnO \rightarrow CO_2 + 2Zn \] ### Step 5: Calculate Overall Enthalpy Change - The overall enthalpy change for the combined reaction is: \[ \Delta H = (-393 \, \text{J}) + (+412 \, \text{J}) = +19 \, \text{J} \] ### Step 6: Conclusion - Since the overall reaction has a positive enthalpy change, it indicates that carbon can indeed reduce zinc oxide to zinc. Therefore, carbon acts as a reducing agent and zinc oxide acts as an oxidizing agent. ### Final Options Analysis 1. **Carbon can reduce zinc oxide to zinc:** **Correct** 2. **Oxidation of carbon is not feasible:** **Incorrect** 3. **Oxidation of zinc is not feasible:** **Incorrect** 4. **Zinc liberates more heat than carbon during oxidation:** **Correct** ### Summary of Correct Options: - The correct options are 1 and 4.

To solve the question regarding the reactions of carbon and zinc with oxygen, we will analyze the given reactions and their enthalpy changes step by step. ### Given Reactions: 1. **Carbon Reaction:** \[ C + O_2 \rightarrow CO_2, \quad \Delta H = -393 \, \text{J} \] ...
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