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pK(a)of a weak acid is defined as :...

`pK_(a)`of a weak acid is defined as :

A

`log K_(a)`

B

`1/logK_(a)`

C

`"log"1/K_(a)`

D

`"-log" 1/K_(a)`

Text Solution

AI Generated Solution

The correct Answer is:
To define the \( pK_a \) of a weak acid, we need to understand the relationship between the acid dissociation constant (\( K_a \)) and \( pK_a \). Here’s a step-by-step explanation: ### Step 1: Understanding Acid Dissociation A weak acid (HA) partially dissociates in water to form its conjugate base (A⁻) and hydronium ions (H₃O⁺). The dissociation can be represented as: \[ HA \rightleftharpoons A^- + H_3O^+ \] ### Step 2: Defining the Acid Dissociation Constant (\( K_a \)) The acid dissociation constant (\( K_a \)) is a measure of the strength of the acid in solution. It is defined by the equilibrium expression: \[ K_a = \frac{[A^-][H_3O^+]}{[HA]} \] where: - \([A^-]\) is the concentration of the conjugate base, - \([H_3O^+]\) is the concentration of hydronium ions, - \([HA]\) is the concentration of the undissociated acid. ### Step 3: Relating \( K_a \) to \( pK_a \) The \( pK_a \) is defined as the negative logarithm of the acid dissociation constant: \[ pK_a = -\log(K_a) \] ### Step 4: Alternative Expression for \( pK_a \) Using properties of logarithms, we can also express \( pK_a \) as: \[ pK_a = \log\left(\frac{1}{K_a}\right) \] ### Conclusion Thus, the \( pK_a \) of a weak acid is defined as: \[ pK_a = -\log(K_a) \quad \text{or} \quad pK_a = \log\left(\frac{1}{K_a}\right) \] ### Final Answer The correct definition of \( pK_a \) of a weak acid is: \[ pK_a = -\log(K_a) \quad \text{or} \quad pK_a = \log\left(\frac{1}{K_a}\right) \]

To define the \( pK_a \) of a weak acid, we need to understand the relationship between the acid dissociation constant (\( K_a \)) and \( pK_a \). Here’s a step-by-step explanation: ### Step 1: Understanding Acid Dissociation A weak acid (HA) partially dissociates in water to form its conjugate base (A⁻) and hydronium ions (H₃O⁺). The dissociation can be represented as: \[ HA \rightleftharpoons A^- + H_3O^+ \] ...
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Knowledge Check

  • pK_(a) of a weak acid is 5.76 and pK_(b) of a weak base is 5.25. What will be the pH of the salt formed by the two ?

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