Home
Class 12
CHEMISTRY
The equivalent conductances of two stron...

The equivalent conductances of two strong electrolytes at infinite dilution in H2O (where ions move freely through a solution) at `25^(@)C`are given below:
`wedge_(CH_(3)COONa^(@) = 91.0Scm^(2)//equ iv` , `wedge_HCl^(@)= 426.25cm^(2)//equiv`
What additional information/quantity one needs to calculate `overset(o)(wedge)` of an aqueous solution of acetic acid?

A

`overset(o)(wedge)` of NaC1

B

`3 overset(o)(wedge)` of `CH_(3)COOK`

C

The limitation equivalent conductance of `H^(+) (wedge_(H^+)^(@))`

D

`overset(o)wedge` of chlorocetic acid `(C1CH_(2)COOH)`

Text Solution

AI Generated Solution

To find the equivalent conductance of acetic acid (\( \overset{o}{\lambda} \) of CH₃COOH) at infinite dilution, we can use Kohlrausch's law, which states that the equivalent conductance of a weak electrolyte can be calculated using the equivalent conductances of its ions and the equivalent conductance of a strong electrolyte that dissociates completely. ### Step-by-Step Solution: 1. **Understand the Given Data**: - The equivalent conductance of sodium acetate (\( \text{CH}_3\text{COONa} \)) at infinite dilution is \( \overset{o}{\lambda}_{\text{CH}_3\text{COONa}} = 91.0 \, \text{S cm}^2/\text{equiv} \). - The equivalent conductance of hydrochloric acid (\( \text{HCl} \)) at infinite dilution is \( \overset{o}{\lambda}_{\text{HCl}} = 426.25 \, \text{S cm}^2/\text{equiv} \). ...
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|76 Videos
  • ELECTROCHEMISTRY

    VMC MODULES ENGLISH|Exercise FUNDAMENTAL|50 Videos
  • ELECTROCHEMISTRY

    VMC MODULES ENGLISH|Exercise Level-2|65 Videos
  • CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES

    VMC MODULES ENGLISH|Exercise JEE ADVANCE (ARCHIVE)|30 Videos
  • ENVIRONMENTAL CHEMISTRY

    VMC MODULES ENGLISH|Exercise JEE Main (Archive)|39 Videos

Similar Questions

Explore conceptually related problems

Calculate, molar conductance of acetic acid using appropriate molar conductances of the electrolytes listed above at infinite dilution in H_(2)O at 25^(@)C :

The equivalent conductances of CH_(3)COONa, HCI "and" NaCI at infinit e dilution are 91,426 an 126 S cm^(2) eq^(-1) respectively at 25^(2)C The equivalent conductance of 1 M CH_(3)COOH solution is 19.55 S cm^(2) eq^(-1) The pH of solution is (pK_(a)=4.74)

Calculate K_(a) of acetic acid it its 0.05N solution has equivalent conductances of 7.36 mho cm^(2) at 25^(@)C (lambda_(CH_(3)COOH)^(oo) = 390.70)

If the equivalent conductance of (M/20) solution of a weak monobasic acid is 25.0 S cm^2 eq^(-1) and at infinite dilution is 500 Scm^2eq^(-1) , then the dissociation constant of the acid is

The equivalent conductivity of N/10 solution of acitic acid at 25^(@)C is 14.3 ohm^(-1) cm^(2) eq^(-1) . Calculate the degree of dissociation of CH_(3)COOH if Lambda_(oo CH_(3)COOH) is 390.71.

The molar conductivities of wedge_(NaOAc)^(@) and wedge_(HCl)^(@) at infinite dilution in water at 25^(@)C are 91.0 and 426.2 S cm^(2)//mol respectively. To calculate wedge_(HOAc)^(@) , the additional value required is :

The equivalent conductances of sodium chloride, hydrochloric acid and sodium acetate at infinite dilution are 126.45, 426,16 and 91.0 ohm^(-1)cm^(2) equiv^(-1) , respectively, at 25^(@)C . Calculate the equivalent conductance of acetic acid at infinite dilution.

At 25^(@)C the equivalent conductance of butanoic acid at infinite dilution is 386.6 ohm^(-1)cm^(2)eq^(-1) . If the ionization consatant is 1.4xx10^(-5) , calculate equivalent conductance of 0.05 N butanoic acid solution at 25^(@)C(ohm^(-1)cm^(2)eq^(-1)) ?

At infinite dilution, the equivalent conductances of CH_(3)COOHa, HCl and CH_(3)COOH are 91, 426 and 391 mho cm^(2)eq^(-1) respectively at 25^(@)C . The equivalent conductance of NaCl at infinite dilution wil be:

The specific conductance of a 0.01 M solution of acetic acid at 298 K is 1.65 xx 10^(-4) "ohm"^(-1)cm^(-1) . The molar conductance at infinite dilution for H^(+) ion and CH_(3)COO^(-) ion are 349.1 "ohm"^(-1) cm^(2 )"mol"^(-1) and 40.9 "ohm"^(-1) cm^(2) "mol"^(-1) respectively. Calculate : (i) Molar conductance of solution (ii) Degree of dissociation of acetic acid (iii) Dissociation constant for acetic acid.

VMC MODULES ENGLISH-ELECTROCHEMISTRY-JEE Main (Archive)
  1. Resistance of a conductivity cell filled with a solution of an electro...

    Text Solution

    |

  2. The cell, Zn | Zn^(2+) (1M) || (1M) | Cu (E(cell)^(@) = 1.10V), was wa...

    Text Solution

    |

  3. The equivalent conductances of two strong electrolytes at infinite dil...

    Text Solution

    |

  4. Given E(Cr^(3+)//Cr)^(@)= 0.72V, E(Fe^(2+)//Fe)^(@)=-0.42V. The potent...

    Text Solution

    |

  5. In a fuel cell, methanol is used as fuel and oxygen gas is used as an ...

    Text Solution

    |

  6. Given : E(Fe^(3+)//Fe)^(@) = -0.036V, E(FE^(2+)//Fe)^(@)= -0.439V. The...

    Text Solution

    |

  7. The Gibbs energy for the decomposition of Al(2)O(3) at 500^(@)C is as ...

    Text Solution

    |

  8. The reduction potential of hydrogen half cell will be negative if :

    Text Solution

    |

  9. The standard reduction potentials for Zn^(2+)//Zn, Ni^(2+)//Ni, and Fe...

    Text Solution

    |

  10. Use the data given in Q.8 and find out which of the following is the ...

    Text Solution

    |

  11. Given below are half-cell reaction: Mn^(2+)+2e^(-) rarr Mn,, E^(@) =...

    Text Solution

    |

  12. The equivalent conductance of NaCl at concentration C and at infinite...

    Text Solution

    |

  13. Resistance of 0.2 M solution of an electrolyte is 50Omega . The specif...

    Text Solution

    |

  14. Two Faraday of electricity is passed through a solution of CuSO(4). Th...

    Text Solution

    |

  15. A variable, opposite external potential(E(ext) is applied to the ce...

    Text Solution

    |

  16. At 298 K, the standard reduction potentials are 1.51 V for MnO(4)^(-) ...

    Text Solution

    |

  17. Galvanization is applying a coating of:

    Text Solution

    |

  18. Oxidation of succinate ion produces ethylene and carbon dioxide gases....

    Text Solution

    |

  19. Identify the correct statement.

    Text Solution

    |

  20. What is the standard reducing potential (E^(@)) for Fe^(3+)to Fe? (Gi...

    Text Solution

    |