Alcoholic `"AgNO"_(3)` does not give precipitate with:

Options

A. `C_(6)H_(5)CH_(2)`Cl
B. `CH_(2)=CH-CH-`Cl
C. `C_(6)H_(5)"Cl"`
D. `(CH_(3))_(3)` CCl

Answer

To solve the question "Alcoholic AgNO₃ does not give precipitate with:", we need to analyze the behavior of each compound when reacted with alcoholic silver nitrate (AgNO₃).

### Step-by-Step Solution:

1. **Understanding the Reaction**: Alcoholic silver nitrate is used to test for the presence of halides. When a halide reacts with AgNO₃, it typically forms a precipitate of silver halide (AgX).

2. **Analyzing Benzyl Chloride (C₆H₅CH₂Cl)**:
- Benzyl chloride can undergo nucleophilic substitution due to the presence of the benzylic carbon.
- When reacted with alcoholic AgNO₃, it forms a benzyl cation (C₆H₅CH₂⁺) and precipitates silver chloride (AgCl).
- **Conclusion**: Benzyl chloride gives a precipitate.

3. **Analyzing Allyl Chloride (CH₂=CH-CH₂Cl)**:
- Allyl chloride can also undergo nucleophilic substitution.
- Upon reaction with alcoholic AgNO₃, it forms an allylic cation (CH₂=CH-CH₂⁺) and precipitates silver chloride (AgCl).
- **Conclusion**: Allyl chloride gives a precipitate.

4. **Analyzing Chlorobenzene (C₆H₅Cl)**:
- Chlorobenzene does not undergo nucleophilic substitution easily due to the stability of the aromatic ring.
- When reacted with alcoholic AgNO₃, it does not form a cation and does not precipitate silver chloride.
- **Conclusion**: Chlorobenzene does not give a precipitate.

5. **Analyzing Tertiary Butyl Chloride ((CH₃)₃CCl)**:
- Tertiary butyl chloride can undergo nucleophilic substitution due to the stability of the tertiary cation.
- When reacted with alcoholic AgNO₃, it forms a tertiary butyl cation and precipitates silver chloride (AgCl).
- **Conclusion**: Tertiary butyl chloride gives a precipitate.

### Final Answer:
The compound that does not give a precipitate with alcoholic AgNO₃ is **Chlorobenzene (C₆H₅Cl)**.