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The shape of XeF(4) molecule is...

The shape of `XeF_(4)` molecule is

A

Tetrahedral

B

Trigonal bipyramidal

C

Square pyramidal

D

Pentagonal bipyramidal

Text Solution

AI Generated Solution

The correct Answer is:
To determine the shape of the `XeF4` molecule, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Central Atom**: The central atom in `XeF4` is xenon (Xe). 2. **Determine Valence Electrons**: - Xenon (Xe) has 8 valence electrons. - Each fluorine (F) atom has 7 valence electrons, and since there are 4 fluorine atoms, we have \(4 \times 7 = 28\) valence electrons from fluorine. - Total valence electrons = \(8 + 28 = 36\). 3. **Draw the Lewis Structure**: - Place Xe in the center and surround it with 4 F atoms. - Form single bonds between Xe and each F atom. Each bond uses 2 electrons, so \(4 \times 2 = 8\) electrons are used for bonding. - Remaining electrons = \(36 - 8 = 28\) electrons. - Distribute the remaining electrons to the fluorine atoms to fulfill their octet (each F needs 8 electrons). 4. **Account for Lone Pairs**: - After bonding, the xenon atom has 4 bond pairs (one for each Xe-F bond) and 2 lone pairs of electrons. - This gives a total of 6 electron pairs around the xenon atom. 5. **Determine Hybridization**: - The presence of 6 electron pairs (4 bond pairs + 2 lone pairs) indicates hybridization of `sp^3d^2`. 6. **Determine Molecular Geometry**: - The electron pair geometry for `sp^3d^2` is octahedral. - However, because there are 2 lone pairs, the molecular shape is affected. - The lone pairs will occupy positions opposite each other to minimize repulsion, leading to a square planar arrangement of the fluorine atoms. 7. **Conclusion**: The shape of the `XeF4` molecule is square planar. ### Final Answer: The shape of `XeF4` is square planar.
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