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For 2SO(2)(g)+O(2)(g) hArr 2SO(3)(g),K(p...

For `2SO_(2)(g)+O_(2)(g) hArr 2SO_(3)(g),K_(p)=3.4`. At an instant, the partial pressures of `SO_(2), O_(2) and SO_(3)` were found to be 0.41 atm, 0.16 atm and 0.57 atm respectively. Comment on the status of equilibrium process.

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To solve the problem, we need to analyze the given reaction and the provided partial pressures to determine the status of the equilibrium process. ### Step-by-Step Solution: 1. **Write the Balanced Chemical Equation:** The balanced chemical equation is: \[ 2SO_2(g) + O_2(g) \rightleftharpoons 2SO_3(g) \] 2. **Identify the Given Values:** - \( K_p = 3.4 \) - Partial pressures at a certain instant: - \( P_{SO_2} = 0.41 \, \text{atm} \) - \( P_{O_2} = 0.16 \, \text{atm} \) - \( P_{SO_3} = 0.57 \, \text{atm} \) 3. **Calculate the Reaction Quotient \( Q \):** The reaction quotient \( Q \) is calculated using the formula: \[ Q = \frac{(P_{SO_3})^2}{(P_{SO_2})^2 \cdot (P_{O_2})} \] Substituting the values: \[ Q = \frac{(0.57)^2}{(0.41)^2 \cdot (0.16)} \] - Calculate \( (0.57)^2 = 0.3249 \) - Calculate \( (0.41)^2 = 0.1681 \) - Now substitute: \[ Q = \frac{0.3249}{0.1681 \cdot 0.16} \] - Calculate \( 0.1681 \cdot 0.16 = 0.026896 \) - Finally, calculate \( Q \): \[ Q = \frac{0.3249}{0.026896} \approx 12.07 \] 4. **Compare \( Q \) with \( K_p \):** We have: - \( Q \approx 12.07 \) - \( K_p = 3.4 \) Since \( Q > K_p \), we can conclude that the reaction quotient is greater than the equilibrium constant. 5. **Determine the Direction of the Shift:** According to Le Chatelier's principle: - If \( Q > K_p \), the reaction will shift to the left (toward the reactants) to reach equilibrium. 6. **Conclusion:** The equilibrium process is currently not at equilibrium and will shift in the backward direction (toward the formation of \( SO_2 \) and \( O_2 \)). ### Summary: The reaction is not at equilibrium because \( Q (12.07) > K_p (3.4) \). Therefore, the equilibrium will shift to the left.
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