Home
Class 12
CHEMISTRY
In octahedral holes (voids):...

In octahedral holes (voids):

A

A simple triangular void surrounded by four spheres

B

A bi-triangular void surrounded by four spheres

C

A bi-triangular void surrounded by six spheres

D

A bi-triangular void surrounded by eight spheres

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding octahedral holes (voids), we can follow these steps: ### Step 1: Understand the Structure of Octahedral Voids Octahedral voids are formed in a crystal lattice where atoms are arranged in a specific geometric configuration. In a typical face-centered cubic (FCC) lattice, octahedral voids are located at the center of the cube and at the edges. ### Step 2: Visualize the Arrangement In an FCC lattice, consider the arrangement of atoms: - Atoms are located at each corner of the cube and at the center of each face. - The octahedral void is created by the arrangement of these atoms. ### Step 3: Identify the Surrounding Atoms In the case of octahedral voids: - There are 6 atoms surrounding the void. - These atoms are positioned at the vertices of an octahedron. ### Step 4: Analyze the Options Given the options, we need to identify which one correctly describes the octahedral void: - The correct description will mention that the void is surrounded by 6 spheres (atoms). ### Step 5: Select the Correct Option Based on the analysis, the correct option is: **C: A bi-triangular void surrounded by six spheres.** ### Final Answer The correct option regarding octahedral holes is **C**. ---
Doubtnut Promotions Banner Mobile Dark
|

Topper's Solved these Questions

  • THE SOLID STATE

    VMC MODULES ENGLISH|Exercise EXERCISE-H|10 Videos
  • THE SOLID STATE

    VMC MODULES ENGLISH|Exercise EXERCISE-I|10 Videos
  • THE SOLID STATE

    VMC MODULES ENGLISH|Exercise EXERCISE-F|10 Videos
  • SURFACE CHEMISTRY

    VMC MODULES ENGLISH|Exercise PRACTICE EXERCISE|9 Videos
  • THEORY OF SOLUTIONS

    VMC MODULES ENGLISH|Exercise JEE Advanced (Archive)|31 Videos

Similar Questions

Explore conceptually related problems

In which of the following pairs of structures, tetrahedral as well as octahedral holes are found?

The numbers of tetrahedral and octahedral holes in a ccp array of 100 atoms are respectively

Knowledge Check

  • Assertion: In crystal lattice, the size of the tetrahedral hole is large than an octahedral hole. Reason: The cations occupy more space than anions in crystal packing.

    A
    If both assertion and reason are true and reason is the correct explanation of assertion.
    B
    If both assertion and reason are true, but reason is not the correct explanation of assertion.
    C
    If assertion is true, but reason is false.
    D
    If both assertion and reason are false
  • Similar Questions

    Explore conceptually related problems

    How many nearest neighbours are there in an atom or ion for an octahedral hole of a closed packed structure?

    In a crystalline solid, having formula AB_(2)O_(4) oxide ions are arranged in cubic close packed lattice while cations A are present in tetrahedral voids and cations B are present in octahedral voids. (a) What percentage of the tetrahedral voids is occupied by A? (b) What percentage of the octahedral voids is occupied by B ?

    In a crystalline solid, having formula AB_(2)O_(4) oxide ions are arranged in cubic close packed lattice while cations A are present in tetrahedral voids and cations B are present in octahedral voids. (a) What percentage of the tetrahedral voids is occupied by A? (b) What percentage of the octahedral voids is occupied by B ?

    In the unit cell of KCl (NaCl type), Cl^(-) ions constitute ccp and K^(+) ion fall into the octahedral holes. These holes are:

    How will you distinguish between the following pairs of terms: (i) Tetrahedral and octahedral voids (ii) Crystal lattice and unit cell

    The maximum ra dius of sphere that can be fitted in the octahedral hole of cubical closed packing of sphere of raius r is

    What is the coordination number of octahedral voids?