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Why does physisorption decrease with inc...

Why does physisorption decrease with increase of temperature ?

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Why does physisorption decrease with the increase of temperature ?

Which of the following statements is not true? a. Both physisorption and chemisorption are exothermic. b. Physisorption occurs with increase of free energy. c. Physisorption requires low activation energy but chemisorption requires high activation energy. d. The magnitude of chemisorption increases and that of physisorption decreases with rise in temperature.

Knowledge Check

  • The correct statement(s) pertaining to the adsorption of a gas on a solid surface is(are) (i) adsorption is always exothermic (ii) physisorption may transform into chemsisorption transform into chemisorption at high temperature (iii) physisorption increases with increasing temperature but chemisorption decreases with increasing temperature . (iv) chemisorption is more exothermic than physisorption , however it is very slow due to higher energy of activation.

    A
    (i) and (iv) only
    B
    (ii) and (iii) only
    C
    (i),(ii) and (iv) only
    D
    All of these.
  • Assertion : The angle of contact of a lilquid with a solid decreases with increase in temperature. Reason : With increase in temperature, the surface tension of the liquid increases.

    A
    If both assertion and reason are true and reason is the correct explanation of assertion.
    B
    If both assertion and reason are true but reason is not the correct explanation of assertion.
    C
    If assertion is true and reason is false.
    D
    If both assertion and reason are false.
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    The rate of physisorption increases with (a)Decrease in temperature (b)Increase in temperature (c)Both A and B (d)None of these

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    Name a substance whose resistance decreases with the increase in temperature.

    Assertion (A): Ionic conductivities increase with increase of temperature and pressure. Reason (R): Viscosity of water decreases with increasew of temperature and increases with the increases of pressure.

    Assertion (A) : The value of K for a reaction may increase or decrease with increase in temperature depending upon whether the reaction is exothermic or endothermic. Reason (R) : With increase in temperature, the extent of reaction increases.