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Silver mirror is a test for :...

Silver mirror is a test for `:`

A

Aldehydes

B

Thio alcohols

C

Amines

D

Ethers

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**Step-by-Step Solution:** 1. **Understanding the Silver Mirror Test:** The silver mirror test is a qualitative test used to distinguish between aldehydes and ketones. It is specifically used to identify the presence of aldehydes. 2. **Reagents Used:** The reagent used in this test is ammonical silver nitrate, which has the formula Ag(NH3)2NO3. This reagent contains silver ions that can be reduced. 3. **Reaction Mechanism:** When an aldehyde is present, it acts as a reducing agent. The aldehyde is oxidized to a carboxylic acid, while the silver ions in the ammonical silver nitrate are reduced to metallic silver. 4. **Formation of Silver Mirror:** As the reaction proceeds, metallic silver is deposited on the inner surface of the test tube, forming a shiny silver mirror. This is a positive indication for the presence of an aldehyde. 5. **Distinguishing Aldehydes from Ketones:** Ketones do not react with ammonical silver nitrate under the same conditions and therefore do not produce a silver mirror. This is the key difference that allows the test to distinguish between these two functional groups. 6. **Conclusion:** The silver mirror test is a specific test for aldehydes, as they give a positive result by forming a silver mirror, while ketones do not react and thus give a negative result. ---
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Knowledge Check

  • When fructose treated with Tollen's reagent, silver mirror is formed due to reduction of Ag^(o+) by:

    A
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    B
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    A
    `Ph-underset(O)underset(||)(C)-H`
    B
    `Ph-underset(H)underset(|)(N)-OH`
    C
    `Ph-CH_(2)-underset(O)underset(||)(C)-CH_(2)-OH`
    D
    `H_(3)C-C-=CH`
  • Silver mirror test with Tollen's reagent is give by

    A
    `C_(6)H_(5)CHO`
    B
    `CH_(2)=CH-HO`
    C
    `C_(6)H_(5)-CH=CH-CHO`
    D
    all of these
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