Home
Class 12
CHEMISTRY
Explain why Bond dissociation energy of ...

Explain why Bond dissociation energy of `F_2` is less than that of `Cl_2` ?

Text Solution

Verified by Experts

Fluorine atom being smaller in size, the inter-electronic repulsions between the non-bonding electrons present in the 2p-orbitals of fluorine atoms are much larger than similar interelectronic repulsions between the non-bonding electrons present in the relatively larger 3p-orbitals of chlorine atoms.
Promotional Banner

Topper's Solved these Questions

  • SURFACE CHEMISTRY

    BETTER CHOICE PUBLICATION|Exercise Question Bank|94 Videos
  • THE SOLID STATE

    BETTER CHOICE PUBLICATION|Exercise Numerical Problems|66 Videos

Similar Questions

Explore conceptually related problems

Bond dissociation energy of F_2 is less than Cl_2 .

Explain why the internal eneryg of a compressed gas is less than that of a rarefied gas at the same temperature.

Dipole moment of CH_3F is less/more than that of CH_3Cl .

Explain why boiling point of ethylamine is less than that of ethyl alcohol .

Account for the following : Bond energy of F_2 is less than Cl_2 .

Give reasons for the following: Bond enthalpy of F_2 is lower than that of Cl_2 .

BETTER CHOICE PUBLICATION-THE P-BLOCK ELEMENTS-QUESTION BANK
  1. Why does fluoriue show anomalous behaviour in its group ?

    Text Solution

    |

  2. Why are halogens most reactive ?

    Text Solution

    |

  3. Explain why Bond dissociation energy of F2 is less than that of Cl2 ?

    Text Solution

    |

  4. Explain why F-F bond in fluorine is weaker than Cl-Cl bond in chlori...

    Text Solution

    |

  5. Explain the following : HF is a weaker acid than HI.

    Text Solution

    |

  6. Explain the following : Iodine is more soluble in KI solution than i...

    Text Solution

    |

  7. Explain the following : Fluorine does not show positive oxidation st...

    Text Solution

    |

  8. Explain the following : Iodine forms I3^- but F2^ does not form F3^-...

    Text Solution

    |

  9. Explain: Electron gain enthalpy of chlorine is more negative than fluo...

    Text Solution

    |

  10. Why electron affinity of fluorine is less than that of chlorine ?

    Text Solution

    |

  11. Boiling point of HCI is lower than HF . Explain why?

    Text Solution

    |

  12. Why are halogens coloured ?

    Text Solution

    |

  13. Halogens have maximum negative electron gain enthalpy in the respectiv...

    Text Solution

    |

  14. Electron gain enthalpy of chlorine is more negative as compared to flu...

    Text Solution

    |

  15. Considering the parameters such as bond dissociation enthalpy, electro...

    Text Solution

    |

  16. Why is fluorine a very reactive halogen ?

    Text Solution

    |

  17. Account for the following: Among the halogens F2 is the strongest oxid...

    Text Solution

    |

  18. Fluorine exhibits only - 1 oxidation state whereas other halogens exhi...

    Text Solution

    |

  19. Explain why Most metal fluoride are ionic in nature than metal chlo...

    Text Solution

    |

  20. Explain why Hydrogen fluoride is a weaker acid than hydrogen chlorid...

    Text Solution

    |