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Define sp^(2) Hybridisation. Explain the...

Define `sp^(2)` Hybridisation. Explain the structure of Ethylene `(C_(2)H_(4))`.

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`sp^(2)` Hybridisation: The phenomenon of intermixing of one.s d two p orbitals forming three `sp^(2)` hybrid orbitals is hybridisation.
a.`C_(2)H_(4)` (ethylenes): In the formation of enthylene molecule, the two carbon atoms will undergo `sp^(2)` hybridistion in their ex cited states. As a result of which `sp^(2)` hybrid orbitals will form on each of them. All the six hybrid orbitals contain an electron each At first one `sp^(2)` hybrid orbtial of each carbon atom overlap Head -Head forming one sigma bond in between them. Now the remaining four `sp^(2)` hybrid orbitals overlap Head -Head with 1s orbitals of foru H atoms forming four sigma bonds. Now, the unhybridised pure `2p_(z)` orbitals of each carbonatom overlap side wide forming`pi` bond in between them. Thus a double bond in formed in between the two carbon atoms.
Intotal there are five sigma bonds and one pi and bond in ethyiene molecule. The molecule as a whose is palanar.
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Knowledge Check

  • sp^(2) - Hybridisation is involved in the molecule of

    A
    CO
    B
    `CO_(2)`
    C
    `SO_(2)`
    D
    `SO_(3)`
  • The structure of H_(2)O_(2) is

    A
    Planar
    B
    Non-Polar
    C
    Spherical
    D
    Linear
  • In AX_(5) type sof molecule if 'A' undergoes sp^(3)d^(2) hybridisation, then the shape of the molecule is

    A
    T-shape
    B
    Octahedral
    C
    Square pyramidal
    D
    Tetrahedal
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